Results 211 to 220 of about 663,607 (251)

Fungal Bioleaching for Metal Recovery: Recent Progress and Technological Advances. [PDF]

J Fungi (Basel)
Soares AR, Xu X, Baltazar MDPG, Yin WB.
europepmc   +1 more source

Coordinating Mesopore Geometry and Interfacial Water Dynamics for Iron‐Site Evolution in Nitrate Electroreduction

Angewandte Chemie, EarlyView.
Mesopore geometry programs the working‐state interface of Fe single sites during nitrate electroreduction. Hexagonal channels reorganize interfacial water and accompany the reversible evolution of isolated Fe─O4‐like sites toward Fe─O─Fe‐like motifs, promoting successive hydrogenation toward NH3 with a Faradaic efficiency of 99.1%.
Xiangyang Liu, Yingji Zhao, Norman C.‐R. Chen, Kevin C.‐W. Wu, Ho Ngoc Nam, Quan Manh Phung, Asep Sugih Nugraha, Yusuke Asakura, Yusuke Yamauchi   +8 more
wiley   +1 more source

Dual d–p hybridization in Ternary PtGaGe Enables Concurrent Activity and Stability Enhancement for Alkaline Oxygen Reduction

Angewandte Chemie, EarlyView.
A unique dual d–p orbital hybridization strategy was established in a ternary PtGaGe alloy catalyst to overcome the longstanding activity–stability trade‐off in oxygen reduction reaction (ORR). Synergistic hybridization between Ga/Ge p orbitals and Pt d orbitals modulates the Pt electronic structure, optimizes oxygen intermediates adsorption, and ...
Qian Zhang, Jinting Wu, Yong‐Chao Zhang, Lijun Tang, Xingchun Shi, Jian Gao, Tiansheng Mu, Xiaoli Zhang, Xiao‐Dong Zhu   +8 more
wiley   +1 more source

Sub-4-nm Pt₄FeCoNiCu HEI nanocrystals via borophene-mediated co-anchoring for efficient and durable electrocatalysis. [PDF]

Sci Adv
Zeng X, Fang Z, Tian J, Xu Z, Cai H, He H, Zhang Y, Wang B, Liang C, Liu F, Mei B, Li F, He C, Wu J, Yang S.   +14 more
europepmc   +1 more source

Polypyridyl Coordination Motifs as Precursors for Ordered Carbonaceous Frameworks Toward High‐Density Ru Single‐Atom Catalysts

Angewandte Chemie, EarlyView.
Here, we introduce a molecular design principle that fundamentally expands the bottom‐up synthesis of single‐atom catalysts (SACs). Coordinatively flexible polypyridyl units enable bottom‐up formation of ordered carbonaceous frameworks containing atomically dispersed Ru (∼11 wt%) by simple carbonization.
Koki Chida, Tan‐Hao Shi, Takeharu Yoshii, Yuichiro Hayasaka, Yu Gao, Hao Zhang, Nikolay Kosinov, Shigehisa Akine, Kazuhide Kamiya, Kaining Li, Yoshifumi Kondo, Yasutaka Kuwahara, Tomoki Ogoshi, Hirotomo Nishihara   +13 more
wiley   +1 more source

From Metal-Related Public Health Risks to Bioremediation: The Potential of the Polyextremophilic <i>Galdieria</i> spp.-A Systematic Review. [PDF]

Int J Mol Sci
Pozzuoli E, Auciello C, Avilia S, Iovinella M, De Stefano M, Esposito S, Papa S, Ciniglia C.   +7 more
europepmc   +1 more source

Conformationally Switchable Copper(I) Complexes Amplify BODIPY Triplet Photosensitization

Angewandte Chemie, EarlyView.
Coupling a structurally switchable Cu(I) complex to an organic light‐harvesting chromophore boosts photoinduced intersystem crossing via the transient formation of a Cu(II) intermediate. Spectroscopic, physical, computational, and photocatalytic studies support this unique new approach to solar energy upconversion.
Nisha Kamboj, Annabella DeBernardo, Margaret G. Lekan, Nicholas E. Jackson, Lisa Olshansky   +4 more
wiley   +1 more source

Strain Effect Triggers Pt Adaptive Mechanism to Construct Brønsted Acid Microenvironment for Ampere-Level Hydrogen Production From Alkaline Seawater. [PDF]

Angew Chem Int Ed Engl
Li N, Xiao L, Chen A, Zhang H, Cheng H, An X, Kong Q, Feng Y, Liu W, Liu Q, Zhang L, Liu W, Zhou Y, Chen X, Zhao X, Hu G, Wu Y.   +16 more
europepmc   +1 more source

A Conserved Isoleucine Gates the Diffusion of CO and O2 to the Active Site of NiFe CO‐Dehydrogenase

Angewandte Chemie, EarlyView.
A combination of protein film electrochemistry and site‐directed mutagenesis shows that isoleucine 563 (numbering of Thermococcus sp. AM4) gates the arrival of both CO and O2 to the active site of the nickel‐iron CO dehydrogenases. Mutations at this position increase the resistance to O2 at the cost of a slower reaction with CO.
Laura Opdam, Marta Meneghello, Chloé Guendon, Jade Chargelègue, Andrea Fasano, Aurore Jacq‐Bailly, Christophe Léger, Vincent Fourmond   +7 more
wiley   +1 more source

Maximizing Active Site Density in Tin Single‐Site Catalysts for Selective Carbon Dioxide to Formate Electroreduction

Angewandte Chemie, EarlyView.
High‐loading tin single‐site catalysts (>7.5 wt.% Sn) are synthesized using a nitrogen‐enriched carbon scaffold and mechanochemically assisted pyrolysis to stabilize atomically dispersed Sn. The resulting Sn/N‐C‐M catalyst enables highly selective CO2‐to‐formate conversion (>90% FE across 50–500 mA cm−2) with long‐term durability and operando‐verified ...
Katharina Potemkin, Soressa Abera Chala, Chia‐Yu Chang, Keseven Lakshmanan, Meng‐Che Tsai, Tobias Rios Studer, Elnaz Ebrahimi, Nico Achenbach, Rongji Liu, Johannes Biskupek, Ute Kaiser, Bing Joe Hwang, Carsten Streb   +12 more
wiley   +1 more source