Manganese(I)-Catalyzed Cross-Coupling of Ketones and Secondary Alcohols with Primary Alcohols [PDF]
Catalytic cross-coupling of ketones and secondary alcohols with primary alcohols is reported. An abundant manganese-based pincer catalyst catalyzes the reactions.
Suhas Shahaji Gawali +3 more
doaj +3 more sources
Room Temperature Fabrication of Stable, Strongly Luminescent Dion–Jacobson Tin Bromide Perovskite Microcrystals Achieved through Use of Primary Alcohols [PDF]
Lead-free two-dimensional metal halide perovskites have recently emerged as promising light-emitting materials due to their improved stability and attractive optical properties.
Jinsong Qi +4 more
doaj +2 more sources
Electrochemical Aminoxyl-Mediated Oxidation of Primary Alcohols in Lignin to Carboxylic Acids: Polymer Modification and Depolymerization. [PDF]
An electrochemical process has been developed for chemoselective oxidation of primary alcohols in lignin to the corresponding carboxylic acids. The electrochemical oxidation reactions proceed under mildly basic conditions and employ 2,2,6,6-tetramethyl-1-
Rafiee M +3 more
europepmc +2 more sources
The atmospheric relevance of primary alcohols and imidogen reactions [PDF]
Organic alcohols as very volatile compounds play a crucial role in the air quality of the atmosphere. So, the removal processes of such compounds are an important atmospheric challenge.
Hamed Douroudgari +4 more
doaj +2 more sources
Direct Conversion of Primary Alcohols to 1,2-Amino Alcohols: Enantioselective Iridium-Catalyzed Carbonyl Reductive Coupling of Phthalimido-Allene via Hydrogen Auto-Transfer. [PDF]
The first catalytic enantioselective carbonyl (α-amino)allylations are described. Phthalimido-allene 1 and primary alcohols 2a-2z, 2a'-2c' engage in hydrogen auto-transfer-mediated carbonyl reductive coupling by way of (α-amino)allyliridium-aldehyde ...
Spielmann K +3 more
europepmc +2 more sources
Room temperature sensing of primary alcohols via polyaniline/zirconium disulphide [PDF]
Among the primary alcohols, ethanol is referred to as a heavy chemical due to its many applications in a variety of industries. Detection of primary alcohols can be deployed as a non-invasive method in medical diagnosis and safety measures in food ...
Paul Fadojutimi +7 more
doaj +2 more sources
A mutation in the AdhE alcohol dehydrogenase of Clostridium thermocellum increases tolerance to several primary alcohols, including isobutanol, n-butanol and ethanol. [PDF]
Clostridium thermocellum is a good candidate organism for producing cellulosic biofuels due to its native ability to ferment cellulose, however its maximum biofuel titer is limited by tolerance. Wild type C.
Tian L +4 more
europepmc +2 more sources
Metal/oxide interfacial effects on the selective oxidation of primary alcohols. [PDF]
A main obstacle in the rational development of heterogeneous catalysts is the difficulty in identifying active sites. Here we show metal/oxide interfacial sites are highly active for the oxidation of benzyl alcohol and other industrially important ...
Zhao G +10 more
europepmc +2 more sources
Rotaxane-catalyzed aerobic oxidation of primary alcohols [PDF]
Nitroxide radicals are widely utilized as catalysts for the oxidation of primary alcohols. Here, the aerobic catalytic oxidation cycle of nitroxide radicals has been implemented within a mechanically interlocked rotaxane architecture consisting of a ...
Ilario Baù +10 more
doaj +2 more sources
Direct ketone synthesis from primary alcohols and alkenes enabled by a dual photo/cobalt catalysis [PDF]
Catalytic methods to couple alcohol and alkene feedstocks are highly valuable in synthetic chemistry. The direct oxidative coupling of primary alcohols and alkenes offers a streamlined approach to ketone synthesis.
Guanghao Ji, Xinqiang Chen, Jing Zhang
doaj +2 more sources

