Results 151 to 160 of about 17,830 (242)

Photoswitchable Ambiphilicity: Light‐Gated Frustrated Lewis Pair Reactivity and Z‐Type Interaction

Angewandte Chemie, EarlyView.
Light‐controlled ambiphilicity is realized in photoswitchable intramolecular phosphorus/boron Lewis pairs. Reversible switching modulates both the thermodynamics and kinetics of frustrated Lewis‐pair reactivity, enabling light‐gated CO2 binding and release.
Lennart Stoess, Emil L. M. Paulin, Fabian Michel, Lutz Greb   +3 more
wiley   +2 more sources

Facet-Dependent Water Inhibition of Alkanol Dehydration on TiO₂ via Distinct Water-Alkanol Complexes. [PDF]

Angew Chem Int Ed Engl
Hu W, Cai H, Savoy A, Tian J, Kim S, Lin F, Li J, Xu H, Wu Y, Zhang Z, Jaegers N, Wang H, Gao F, Hu J, Wang Y.   +14 more
europepmc   +1 more source

Electrolyte Interfacial Reactivity Regulates Alloying Anode Pulverization

Advanced Energy Materials, EarlyView.
Electrolyte interfacial reactivity governs the degradation of micrometer‐sized alloying anodes by dictating grain refinement and SEI growth. A high‐reactivity ester‐based electrolyte drives pulverization into fine nanoparticles encapsulated by a thick SEI, forming dense electrodes, whereas a low‐reactivity ether‐based electrolyte enables porous ...
Namhyung Kim, Yaobin Xu, Bharat Gwalani, Won‐Gwang Lim, Matthew R. Fayette, Guosheng Li, Mark H. Engelhard, Peiyuan Gao, Yulan Li, Shenyang Hu, Lili Liu, Jiyu Cai, Zonghai Chen, Md Jasim Uddin, Bhuvaneswari M. Sivakumar, Hsin‐Mei Kao, Zihua Zhu, Seoa Kim, Fredrick Omenya, David Reed, Chongmin Wang, Xiaolin Li   +21 more
wiley   +1 more source

Synergistic Silylium‐Ion and Palladium Catalysis Enables Migratory Alkene Silylation With Allylsilanes by Formal C–H/C–Si Metathesis

Angewandte Chemie, EarlyView.
Merging silylium‐ion and palladium catalysis provides a mechanistically distinct route to allylsilanes by formal C–H/Si–H metathesis. Using allylsilanes as silicon proelectrophiles, various allylarenes undergo migrative silylation, selectively yielding (E)‐allylsilanes.
Longhui Duan, Zheng‐Wang Qu, Stefan Grimme, Elisabeth Irran, Hendrik F. T. Klare, Martin Oestreich   +5 more
wiley   +2 more sources

Fe- and Ru-H-Mordenites for Polyethylene Upcycling: Insights from Thermo-Catalytic Pyrolysis and DFT Studies. [PDF]

ACS Sustain Chem Eng
Pandey G, Bepari S, Gupta S, Xie T, Kuila D.   +4 more
europepmc   +1 more source

Structure and Spectroscopic Characterisation of Phenanthroline‐Based Iodobismuthate(III) Complexes Utilised for Raw Acoustic Signal Classification

Advanced Intelligent Discovery, EarlyView.
Memristors based on trimethylsulfonium (phenanthroline)tetraiodobismuthate have been utilised as a nonlinear node in a delayed feedback reservoir. This system allowed an efficient classification of acoustic signals, namely differentiation of vocalisation of the brushtail possum (Trichosurus vulpecula).
Ewelina Cechosz, Gisya Abdi, Andrzej Sławek, Marlena Gryl, Konrad Szaciłowski   +4 more
wiley   +1 more source

Dialkyl Ethers and Sacrificial Zinc: Oxide Synthons for Calcium tert‐Butoxide Formation

Angewandte Chemie, EarlyView.
When treated with dialkyl ethers, [(BDI)Ca‐μ‐H‐Zn(t‐Bu)2(η6‐C7H8)] (BDI = HC{C(Me)NDipp}2 initiates a sequence of twofold ether dealkylation and oxide sequestration as tert‐butoxide in a process predicated on a combination of extreme basicity and a cooperative redox process administered by the dissimilar constituent metals. (Generative AI (ChatGPT) was
Kyle G. Pearce, Agustín Morales, Michael S. Hill, Claire L. McMullin   +3 more
wiley   +2 more sources

Consequences of Medium-Pore Zeolite Constraints for Alkene Cracking-The Case of n-Pentene. [PDF]

Angew Chem Int Ed Engl
Zhao R, Schallmoser S, Haller GL, Sanchez-Sanchez M, Lercher JA.   +4 more
europepmc   +1 more source

Adaptive Hydrogenation of Alkynes Using CO as a Molecular Trigger to Selectively Produce Alkanes or Z‐Alkenes

Angewandte Chemie, EarlyView.
One catalyst for two products: CO acts as a molecular trigger for adaptive alkyne hydrogenation using supported Pd nanoparticles. The catalyst reversibly switches between the formation of alkanes under H2 and Z‐alkenes under H2/CO for 37 structurally diverse alkynes.
Manisha Durai, Lachlan Sharp‐Bucknall, Tim Alexander Schubert, Jacob Johny, John‐Tommes Krzeslack, Walid Hetaba, Walter Leitner, Alexis Bordet   +7 more
wiley   +2 more sources

Scalable ω-Substituted α-Olefins via Living Chain Transfer Telomerization: A Platform for Next Generation Polyolefins. [PDF]

Angew Chem Int Ed Engl
Logue LG, Burrows CM, Wedekind VJ, Kim HC, Sita LR.   +4 more
europepmc   +1 more source