Angewandte Chemie, EarlyView.Merging silylium‐ion and palladium catalysis provides a mechanistically distinct route to allylsilanes by formal C–H/Si–H metathesis. Using allylsilanes as silicon proelectrophiles, various allylarenes undergo migrative silylation, selectively yielding (E)‐allylsilanes.
Longhui Duan +5 more
wiley +2 more sources
Angewandte Chemie, EarlyView.A highly versatile and general strategy is presented for the scalable production of practical quantities of ω‐substituted α‐olefins using tris(ω‐substituted alkyl)aluminum telogens that are readily available through a “green” synthesis from commodity triisobutylaluminum and ethene as the taxogen. These new α‐olefins can be designed and used as monomers
Lauren G. Logue +4 more
wiley +2 more sources
Effect of Propylene Glycol Coolant pH on the Galvanic Corrosion Behavior of 6061 Aluminum Alloy/304 Stainless Steel. [PDF]
Materials (Basel)Miao H +5 more
europepmc +1 more source
Ionic Liquid Electrolytes for Extreme Temperature Conditions: Challenges and Perspective
Angewandte Chemie, EarlyView.Ionic liquids (ILs) have gained great attention as safe electrolyte components in recent years. This review elucidates the temperature effects on IL‐based electrolytes from molecular configurations, physicochemical properties, and interfacial chemistry, raises the challenges and design strategies operating at low‐ and HT, providing valuable guidance ...
En Xie +11 more
wiley +2 more sources
Synthesis of Non-Steroidal Anti-Inflammatory Drugs Pelubiprofen, Loxoprofen, and Carprofen Through Batch and Continuous-Flow Photo-Favorskii Rearrangement. [PDF]
MoleculesFerrario S +4 more
europepmc +1 more source
Thermoresponsive Solid Dispersion to Enhance Dissolution Profile of Atorvastatin Calcium: An Industrially Sustainable Alternative to Conventional Approaches. [PDF]
PharmaceuticsSherif AY, Ibrahim MA.
europepmc +1 more source
Angewandte Chemie, EarlyView.Erneuerbare Guajacole werden durch Phenyliodid(III)diacetat rasch zu maskierten ortho‐Chinonen oxidiert und bilden eine neue Monomerklasse, die mit Multithiolen selektive Michael‐Typ‐Polyadditionen zu Polymeren mit Thiol‐Guajacol‐Verknüpfungen eingeht.
Dominik P. Hoch +7 more
wiley +1 more source
Dialkyl Ethers and Sacrificial Zinc: Oxide Synthons for Calcium tert‐Butoxide Formation
Angewandte Chemie, EarlyView.When treated with dialkyl ethers, [(BDI)Ca‐μ‐H‐Zn(t‐Bu)2(η6‐C7H8)] (BDI = HC{C(Me)NDipp}2 initiates a sequence of twofold ether dealkylation and oxide sequestration as tert‐butoxide in a process predicated on a combination of extreme basicity and a cooperative redox process administered by the dissimilar constituent metals. (Generative AI (ChatGPT) was
Kyle G. Pearce +3 more
wiley +2 more sources
Examining the Effects of Raw Material and Product Prices on the Payback Time and Net Present Value for the Cumene Production Process: Simultaneous Use of SuperPro Designer and Central Composite Design Programs. [PDF]
ACS OmegaYalçın A.
europepmc +1 more source
Angewandte Chemie, EarlyView.One catalyst for two products: CO acts as a molecular trigger for adaptive alkyne hydrogenation using supported Pd nanoparticles. The catalyst reversibly switches between the formation of alkanes under H2 and Z‐alkenes under H2/CO for 37 structurally diverse alkynes.
Manisha Durai +7 more
wiley +2 more sources