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Proton-Conducting Glass Electrolyte
Analytical Chemistry, 2007A new porous glass electrolyte consisting of heteropolyacids, i.e., phosphotungstic acid (PWA) and phosphomolybdic acid, was investigated and was found to yield a remarkably high proton conductivity of 1.014 S cm(-1) at 30 degrees C and 85% relative humidity.
Thanganathan, Uma, Masayuki, Nogami
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Proton conductance of cell membranes
Journal of Theoretical Biology, 1973Abstract Several workers have suggested that cell membranes have a high proton conductance. Our interest in this concept arose from the possibility that the nutrient (submucosal-facing) membrane of the gastric mucosa may have a high proton or hydroxyl ion conductance which would play a role in the regulation of the acid-base balance of the cell.
W S, Rehm +5 more
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Proton diffusion in proton conducting oxides
Phase Transitions, 1996Abstract Quasielastic neutron scattering was used to study the atomistic proton diffusion mechanism in Yb-doped SrCeO3, a proton conducting perovskite, simultaneously in space and time. Proton diffusion consists of a sequence of trapping and free diffusion events.
R. Hempelmann, Ch. Karmonik
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Journal of Applied Physics, 1997
Fast proton conducting glasses have been obtained in Mg(PO3)2 glasses by implantation of protons at 120 keV to a fluence of 1×1018 cm−2. The dc conductivity and the activation energy of the conduction in the implanted glasses are 5×10−4 s cm−1 at room temperature and 0.18 eV, respectively.
H.Hosono +4 more
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Fast proton conducting glasses have been obtained in Mg(PO3)2 glasses by implantation of protons at 120 keV to a fluence of 1×1018 cm−2. The dc conductivity and the activation energy of the conduction in the implanted glasses are 5×10−4 s cm−1 at room temperature and 0.18 eV, respectively.
H.Hosono +4 more
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Annual Review of Materials Research, 2003
▪ Abstract The structural and chemical parameters determining the formation and mobility of protonic defects in oxides are discussed, and the paramount role of high-molar volume, coordination numbers, and symmetry are emphasized. Symmetry also relates to the structural and chemical matching of the acceptor dopant.
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▪ Abstract The structural and chemical parameters determining the formation and mobility of protonic defects in oxides are discussed, and the paramount role of high-molar volume, coordination numbers, and symmetry are emphasized. Symmetry also relates to the structural and chemical matching of the acceptor dopant.
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Composite Proton‐Conducting Membranes for PEMFCs
Fuel Cells, 2007AbstractComposite membranes are of interest for PEMFCs and DMFCs. This paper describes a basic study of the influence of silica on the proton conductivity: (i) added as a filler to poly(vinylidene fluoride‐hexafluoropropylene) and poly(benzimidazole)‐based membranes activated with H3PO4, or (ii) included in the matrix of class II hybrids based on ...
Mustarelli, P +6 more
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Proton conduction in some solids and the fuel cell with a proton conducting electrolyte
International Journal of Hydrogen Energy, 1979Abstract The electrical conductivities of some organic and inorganic solids, such as the simple organic acids, NH4H2PO4, KH2PO4, H3BO3, λ-AIOOH, amine-sulfates and amine-phosphates, have been measured. A relatively high proton conductivity of about 1 × 10−3 ohm−1 cm−1 at 87°C was found in hexamethylenetetramine phosphate.
T TAKAHASHI +4 more
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Protonic and Electronic Conduction in Proton Conductive Solid Oxide Fuel Cells
MRS Proceedings, 2011ABSTRACTProtons can fit into the perovskite structure because the O-O distance is approximately that of ice. However, to achieve charge balance, -2e charge must be added for every two protons added. If O2- vacancies are introduced, for instance by doping barium cerate with yttrium to obtain ${\it Ba}^{2 + } {\it Ce}_{1 - {\it x}}^{4 + } {\it Y}_{\it x}^
V. Hugo Schmidt, Chih-Long Tsai
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Tuning proton conductivity and energy barriers for proton transfer
The Journal of Chemical Physics, 2021Proton transport is critical for many technologies and for a variety of biochemical and biophysical processes. Proton transfer between molecules (via structural diffusion) is considered to be an efficient mechanism in highly proton conducting materials. Yet, the mechanism and what controls energy barriers for this process remain poorly understood.
Amanda R. Young-Gonzales +2 more
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Angewandte Chemie International Edition, 2012
Parasitic current seems to be the cause for the "highest proton conductivity" of a material reported to date. Kreuer and Wohlfarth verify this hypothesis by measuring the conductivity of the same materials after preparing them in a different way. They further explain the limits of proton conductivity and comment on the problems of determining the ...
Kreuer, K., Wohlfarth, A.
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Parasitic current seems to be the cause for the "highest proton conductivity" of a material reported to date. Kreuer and Wohlfarth verify this hypothesis by measuring the conductivity of the same materials after preparing them in a different way. They further explain the limits of proton conductivity and comment on the problems of determining the ...
Kreuer, K., Wohlfarth, A.
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