Results 251 to 260 of about 269,863 (349)

Strain‐Release Pentafluorosulfanylation of Carbonyl‐Containing Disubstituted Bicyclobutanes: A Fortuitous Path to SF5‐Containing Oxa[2.1.1]bicyclohexanes

open access: yesAngewandte Chemie, EarlyView.
A regio‐ and diastereoselective method for strain‐release pentafluorosulfanylation of carbonyl‐containing 1,3‐disubstituted [1.1.0]bicyclobutanes (BCBs) was developed that led to several fortuitous discoveries. For instance, the resultant SF5‐cyclobutanes (SF5‐CBs) exhibit close SF5⋯C═X contacts (X = C, N, O) and provide synthetic access to a new class
Alexander M. Stephens   +9 more
wiley   +1 more source

Selective Nitrate Transmembrane Transport Through Adaptive Weak C─H Bonding Cyanostilbene Water Channels

open access: yesAngewandte Chemie, EarlyView.
Here we demonstrate that weak HB CH donor cyanostilbenes promote water/ion transport through their ability to form less‐ordered transient water channels within the lipid bilayer with increased water permeability and NO3−/ Cl− selectivity. ABSTRACT Transmembrane water transport strongly depends on how dynamic, translocating water clusters are stabilized
Ioan Stroia   +6 more
wiley   +1 more source

Positive Electrochemical Potentials Induce Enhanced Chemoselectivity and Activity in the Thermocatalytic Hydrogenation of 3‐Nitrostyrene

open access: yesAngewandte Chemie, EarlyView.
Induced by positive electrochemical potentials, thermocatalytic hydrogenation (TCH) of 3‐nitrostyrene with H2 delivers one single product with six‐fold enhanced yield. The enhanced selectivity and activity originate from changes in the adsorption geometry of 3‐nitrostyrene and in the surface concentration of 3‐nitrostyrene and hydrogen via a concurrent
Yunfei Jiao   +2 more
wiley   +1 more source

Crosslinking of Linear Polyimines Into Aminal‐Linked Porous Organic Polymers for C2 Hydrocarbon/Methane Separation

open access: yesAngewandte Chemie, EarlyView.
Crosslinking of linear polyimines with aromatic diamines via nucleophilic addition converts nonporous polyimine precursors into aminal‐linked porous networks, offering a new strategy for synthesizing porous organic polymers. The resulting materials exhibit high C2 hydrocarbon adsorption capacity, excellent selectivity over CH4, and durable cyclic ...
Xuejie Li   +4 more
wiley   +1 more source

Materials Engineering for High Performance and Durability Proton Exchange Membrane Water Electrolyzers. [PDF]

open access: yesACS Appl Energy Mater
García-Salaberri PA   +17 more
europepmc   +1 more source

Slowing Down Water: Enhanced and Cation‐responsive MRI Contrast

open access: yesAngewandte Chemie, EarlyView.
The controlled modification of mesoporous silica nanoparticle side walls with kosmotropic motifs supports an ability to reduce water diffusive mobility and dramatically increase MRI contrast to levels unprecedented for highly kinetically stable Gd‐DOTA configurations (both q = 1 and q = 0).
Connor M. Ellis   +5 more
wiley   +1 more source

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