Results 141 to 150 of about 464,016 (298)
Exchange coupling states of cobalt complexes to control proton-coupled electron transfer
Nature CommunicationsThe electrochemical proton reactivity of transition metal complexes receives significant attentions. A thorough understanding of proton-coupled electron transfer (PCET) pathways is essential for elucidating the mechanism behind a proton reduction ...
Jueun Lee, Junseong Lee, Junhyeok Seo
doaj +1 more source
Virtual Issue on Proton Transfer [PDF]
The Journal of Physical Chemistry B, 2021 openaire +2 more sources
Advanced Functional Materials, EarlyView.Electrochemical CO2 reduction (ECR) to formate is a promising route for sustainable chemical production. Herein, we report the synthesis catalysed byBi‐HfO2@C. The AIMD simulations, DFT calculations, and in situ SEIRAS measurements show that the modification of HfO2 on the Bi surface steers the interfacial water to adopt a favorable hydrogen‐down (OH2↓)
Xiao‐Dong Guo +7 more
wiley +1 more source
Advanced Functional Materials, EarlyView.Hydroxyl‐terminated MXene is integrated with a redox‐active covalent organic framework through electrostatic self‐assembly followed by hydrothermal treatment to construct MXene/COF heterostructures with a built‐in interfacial electric field. Termination‐controlled interfacial electronic modulation induces charge redistribution and favorable band ...
Cheru Fekadu Molla +4 more
wiley +1 more source
Kinetic Regimes of Hydrogen Absorption in Thin Films
Advanced Functional Materials, EarlyView.Knowledge of the hydrogen incorporation mechanisms in thin layers in relation to the amount absorbed is essential to design coatings and devices compatible with hydrogen‐based technologies. A combination of simultaneous in situ methods gives detailed insight into the hydrogenation of a prototypical hydrogen absorber layer in a time‐dependent manner ...
Laura Guasco +7 more
wiley +1 more source
Advanced Functional Materials, EarlyView.A monolayer graphene/phosphoric‐acid mixed proton‐electron conducting membrane combines proton‐conducting nanoconfined acid channels with electron‐conducting graphene nanosheets for efficient high‐temperature hydrogen purification. The membrane achieves nearly 100% H2/CO2 selectivity and 69 GPU hydrogen permeance at 250°C, arising from synergistic ...
Kaiqiang He +8 more
wiley +1 more source
Assembly of Cell‐Seeded 3D Printed Hydrogel Modules with Perfusable Channel Networks
Advanced Functional Materials, EarlyView.Macroscale assembly was utilized to prepare perfusable tissue constructs from individually 3D printed hydrogel modules with embedded branched channel networks and port arrays for cell seeding. Novel multi‐material bioreactors were fabricated to facilitate the gluing of individual modules and the perfusion culture of assembled modular constructs seeded ...
Zachary J. Geffert +10 more
wiley +1 more source
X‐Functionality–Driven Photocatalytic Hydrogen Evolution in 2D 4‐X‐PEA2SnI4 Perovskites
Advanced Functional Materials, EarlyView.We report a water‐based synthesis of 2D 4‐X‐PEA2SnI4 perovskite microcrystals with prominent photocatalytic (PC) activity for H2 production. The synergy between organic functionalization and HI‐derived iodide scavenges holes suppress octahedral distortion, and favor electron accumulation, enabling a PC H2 evolution ∼20 µmol·g−1 and long‐term stability ...
Taeyeon Kim +21 more
wiley +1 more source
Quantum-Indeterminate Proton Positions in Ultrafast Excited-State Intramolecular Proton Transfer. [PDF]
J Phys Chem LettLee M, Lee C, Kim J.
europepmc +1 more source
Curvature‐Tuned Friction at Electrified Ionic Liquid Interfaces
Advanced Functional Materials, EarlyView.Graphene curvature plays a key role in friction electrotunability at single‐asperity contacts lubricated by ionic liquids. A 9 nm radius yields stronger tunability than larger radii, with distinct friction coefficients at low and high loads indicating a shift in the slippage plane.
Wei Song +6 more
wiley +1 more source