Results 111 to 120 of about 168,635 (283)
For the first time, a highly sensitive electrochemical biosensor based on SiO2‐based hairy particles with a grafted PDMAEMA polymer brush containing a quantifiable and large amount of immobilized Laccase is reported. The fabricated biosensor exhibits a sensitivity of 0.14 A·m⁻¹, a limit of detection (LOD) of 0.1 µm, and a detection range of 0.3–750 µm,
Pavel Milkin +7 more
wiley +1 more source
Modulating Electrochemical CO2 Reduction Pathways via Interfacial Electric Field
Engineering interfacial electric fields in Cu/ITO electrodes enables precise control of CO2 reduction pathways. Charge transfer from Cu to ITO generates positively charged Cu species that steer selectivity from ethylene toward methane. This work demonstrates how interfacial electric‐field modulation can direct reaction intermediates and transform ...
Mahdi Salehi +7 more
wiley +1 more source
Theoretical Study on the Protonation of Cucurbit[7]uril
By using quantum mechanical DFT calculations, the most probable structures of the cucurbit[7]urilH3O+ and cucur-bit[7]uril'(H3O+)2 cationic complex species were derived. In these two complexes having a plane symmetry, each of the considered H3O+ cations
Emanuel Makrlík +2 more
doaj
Electroactive Metal–Organic Frameworks for Electrocatalysis
Electrocatalysis is crucial in sustainable energy conversion as it enables efficient chemical transformations. The review discusses how metal–organic frameworks can revolutionize this field by offering tailorable structures and active site tunability, enabling efficient and selective electrocatalytic processes.
Irena Senkovska +7 more
wiley +1 more source
Photoswitching Conduction in Framework Materials
This mini‐review summarizes recent advances in state‐of‐the‐art proton and electron conduction in framework materials that can be remotely and reversibly switched on and off by light. It discusses the various photoswitching conduction mechanisms and the strategies employed to enhance photoswitched conductivity.
Helmy Pacheco Hernandez +4 more
wiley +1 more source
Isolation and X-ray Structures of Labile Benzoic- and Acetic-Acidium Carbocations [PDF]
New carbocationic salts (via O-protonation of substituted benzoic acids) are prepared for the first time by controlled hydration of the corresponding benzoylium salts and isolated in pure crystalline form.
Davlieva, M. G. +3 more
core +1 more source
Backbone Heterojunction Photocatalysts for Efficient Sacrificial Hydrogen Production
Herein, a ‘single‐component’ organic semiconductor photocatalyst is presented in which a molecular donor is bonded to a polymer acceptor. The resultant material demonstrates exceptional photocatalytic activity for hydrogen evolution in aqueous triethylamine with an outstanding external quantum efficiency of 38% at 420 nm.
Richard J. Lyons +11 more
wiley +1 more source
Acceleration of Nucleophilic CH Activation by Strongly Basic Solvents [PDF]
(IPI)Ru(II)(OH)_n(H_2O)_m, 2, where IPI is the NNN-pincer ligand, 2,6-diimidizoylpyridine, is shown to catalyze H/D exchange between hydrocarbons and strongly basic solvents at higher rates than in the case of the solvent alone.
Goddard, William A., III +4 more
core +1 more source
Relativistic proton-proton scattering
Abstract In this paper we study elastic p-p scattering in the low-energy range. Relativistic off-shell integral equations for the T -matrix are derived from relativistic scattering theory and a technique for obtaining solutions is discussed explicitly. A field theoretic potential is constructed within the framework of one-boson-exchange model.
openaire +1 more source
Proton-Proton Scattering at 340 Mev
Measurements of the proton-proton differential scattering cross section using 340-Mev protons show a cross section approximately constant between 41\ifmmode^\circ\else\textdegree\fi{} and 90\ifmmode^\circ\else\textdegree\fi{} in the center of mass system. Two methods of counting the scattered protons have been used.
Chamberlain, Owen, Wiegand, Clyde
openaire +4 more sources

