Results 111 to 120 of about 112,578 (285)

Self‐Assembled Crystalline Peptoid Nanomaterials as Metal‐Free Enzyme Mimics for Enhanced Carbon Dioxide Hydration and Precipitation

open access: yesAdvanced Functional Materials, EarlyView.
Inspired by metal‐free carbonic anhydrases (CAs) that achieve efficient catalysis without metal cofactors, we herein report a sequence‐defined supramolecular peptoid platform that mimics metal‐free CAs and exhibits hydrolytic activity via a supramolecular assembly‐mediated proton‐transfer mechanism.
Progyateg Chakma   +8 more
wiley   +1 more source

Protonation states of the histidine.

open access: yes, 2014
Protonation states of the histidine.
William Tiznado (596273)   +4 more
core   +1 more source

Decoupling Li+ Transport in Self‐Healing Polymer Dual‐Salt Electrolytes for Room Temperature Lithium Metal Batteries

open access: yesAdvanced Functional Materials, EarlyView.
A self‐healable polymer matrix, crosslinked via dynamic imine bonds, is synergistically coupled with a LiPF6–LiDFOB dual‐salt system to decouple Li+ from the polymer matrix, enabling fast Li+ transport. This strategy offers an effective pathway toward high‐performance, next‐generation gel‐polymer‐based Li‐metal batteries.
Soumallya Banerjee   +10 more
wiley   +1 more source

Approche théorique des mécanismes de protonation

open access: yes, 1975
La méthode CNDO/2 avec optimisation de l’ensemble des paramètres géométriques a été appliquée avec succès à l’étude de la protonation des énamines. Elle permet d’expliquer d’une manière satisfaisante l’aspect thermodynamique du problème : équilibres ...
Alain Dargelos   +3 more
core   +1 more source

Ga–O–Pt Electronic Bridges Bypass Single‐Site Constraints for pH‐Universal Hydrogen Evolution

open access: yesAdvanced Functional Materials, EarlyView.
Well‐defined oxygen‐bridged Ga–O–Pt catalysts are constructed for pH‐universal hydrogen evolution, highlighting the relationship between oxygen‐bridged electronic coupling, rapid surface hydrogen redistribution, and superior catalytic performance. ABSTRACT Single‐site descriptors often fail to capture hydrogen evolution on heterometallic interfaces ...
Rui Wang   +8 more
wiley   +1 more source

Azobenzene protonation as a tool for temperature sensing

open access: yesBeilstein Journal of Organic Chemistry
Azobenzenes can be protonated at one of the azo nitrogen atoms, leading to significant changes in their absorption and photochemical properties. While azobenzene protonation has been recently used as a tool in photoswitching studies, the factors ...
Antti Siiskonen   +2 more
doaj   +1 more source

Reaction‐Time pH Stabilization by Poly(acrylic acid) with Ethanol‐Mediated Growth Control for Efficient Hydrothermal Sb2(S,Se)3 Solar Cells

open access: yesAdvanced Functional Materials, EarlyView.
Poly(acrylic acid) acts as a reaction‐time pH buffer during hydrothermal Sb2(S,Se)3 growth through its COOH/COO‐ equilibrium. When combined with ethanol‐regulated growth, this buffering strategy reduces Sb‐O related surface disorder, improves local electronic uniformity and carrier collection, and increases the champion solar‐cell efficiency to 10.25%,
Juhee Lee   +7 more
wiley   +1 more source

Chiral phosphoric acid-catalyzed asymmetric protonation reactions of vinylheteroaryls [PDF]

open access: yes
This thesis describes investigations into the chiral phosphoric acid-catalyzed aza-Michael addition-asymmetric protonation between arylamines and various α-substituted vinylheterocycles.
Ashford, Matthew
core   +1 more source

Magneto‐Ionic Devices With Polymer‐Based Electrolytes

open access: yesAdvanced Functional Materials, EarlyView.
Polymer electrolytes are introduced for magneto‐ionic devices based on hydroxide and hydrogen ions. The magneto‐ionic effect results in a pronounced voltage‐controlled variation of coercivity in both devices. The switching speed is in the range of 100 ms.
Markus Gößler   +3 more
wiley   +1 more source

Oxygen Evolution Electrocatalysts with Trinuclear, Mixed‐Valence Iron Motifs on Electronically Aligned Carbon Dots

open access: yesAdvanced Functional Materials, EarlyView.
Trinuclear iron oxo‐bridged catalytic ensembles stabilized by aspartic‐acid‐derived carbon dots provide an effective platform for alkaline oxygen evolution. Mixed‐valence charge balancing, inner‐sphere charge transport, and work‐function alignment within the N/O‐rich carbon framework promote cooperative Fe‐site chemistry and efficient OER ...
Megha A. Deshmukh   +13 more
wiley   +1 more source

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