Results 111 to 120 of about 1,005,462 (289)

Mixed‐Metal Promotion in a Manganese‐Molybdenum Oxynitride as Catalyst to Integrate C─C and C─N Coupling Reactions for the Direct Synthesis of Acetonitrile from Syngas and Ammonia

open access: yesAdvanced Materials, EarlyView.
Transition metal oxy/carbo‐nitrides show great promise as catalysts for sustainable processes. A Mn‐Mo mixed‐metal oxynitride attains remarkable performance for the direct synthesis of acetonitrile, an important commodity chemical, via sequential C─N and C─C coupling from syngas (C1) and ammonia (N1) feedstocks.
M. Elena Martínez‐Monje   +7 more
wiley   +1 more source

A study of the applicability of nucleation theory to quasi-thermodynamic transitions of second and higher Ehrenfest-order [PDF]

open access: yes
The applicability of classical nucleation theory to second (and higher) order thermodynamic transitions in the Ehrenfest sense has been investigated and expressions have been derived upon which the qualitative and quantitative success of the basic ...
Barker, R. E., Jr., Campbell, K. W.
core   +1 more source

Role of Liquid Composition in the Transient Liquid Assisted Growth of Superconducting YBa2Cu3O7‐δ Films

open access: yesAdvanced Materials, EarlyView.
The Y supersaturation in the [Ba‐Cu(I/II)‐O] transient liquid composition is the driving force toward YBCO nucleation and growth in TLAG. Tuning the initial (Ba:Cu) molar ratio in the ink composition determines the YBCO epitaxial nucleation through supersaturation control.
Lavinia Saltarelli   +12 more
wiley   +1 more source

Microscopic Insights into Magnetic Warping and Time‐Reversal Symmetry Breaking in Topological Surface States of Rare‐Earth‐Doped Bi2Te3

open access: yesAdvanced Materials, EarlyView.
Magnetic doping of the topological insulator Bi2Te3 with erbium adatoms induces out‐of‐plane magnetism and breaks time‐reversal symmetry, opening a Dirac gap and driving a Fermi surface transition from hexagonal to star‐of‐David geometry. Microscopy, spectroscopy, and magnetic dichroism reveal atomically controlled magnetic interactions that tailor the
Beatriz Muñiz Cano   +18 more
wiley   +1 more source

Revealing How Acid Sites Enhance the Electrocatalytic Glycerol Oxidation Performance on Pt Loaded Zeolite‐Carbon Composite Materials

open access: yesAdvanced Materials, EarlyView.
In the work reported herein, the catalytic effects of acid sites on electrocatalytic glycerol oxidation reaction are investigated by using a novel catalytic material system that integrates Pt metal sites with acidic Al sites. Abstract The catalytic role and function of acid sites in solid acid catalysts, such as zeolites, are well understood in the ...
Ju Ye Kim   +11 more
wiley   +1 more source

Isotherm and kinetic models of SO2 adsorption on palm kernel shell-activated carbon and xerogel blends: Effect of flow rate and contact time

open access: yesResults in Engineering
Sulphur dioxide (SO2) is released into the atmosphere when coal-fired power plants run, which may substantially impair the environment. SO2 in flue gas causes respiratory difficulties and acid rain, and as energy consumption rises, the amount of SO2 ...
Ali Mohamed Saleh   +9 more
doaj   +1 more source

Non‐Destructive Laser Nanopatterning of Superconducting Heterostructures in Topological Sn Thin Films

open access: yesAdvanced Materials, EarlyView.
We demonstrate successful fabrication of high‐quality α‐Sn/β‐Sn planar nanostructures with arbitrary shapes by focused laser irradiation on topological Dirac semimetal α‐Sn thin films. The irradiated regions transform into atomically smooth, superconducting β‐Sn with a critical temperature of 3.7 K.
Le Duc Anh   +5 more
wiley   +1 more source

Unravelling the Secret of Sulfur Confinement and High Sulfur Utilization in Hybrid Sulfur‐Carbons

open access: yesAdvanced Materials, EarlyView.
Thermal condensation of inverse vulcanized sulfur‐carbon hybrids enables a bottom‐up sulfur confinement strategy, in which a protective carbon phase is progressively constructed around sulfur species. The resulting carbon nanodomains covalently tether sulfur chains and stabilize radical intermediates. This integrated architecture effectively suppresses
Tim Horner   +9 more
wiley   +1 more source

Adaptive Twisting Metamaterials

open access: yesAdvanced Materials, EarlyView.
This work introduces torque‐controlled twisting metamaterials as a transformative platform for adaptive crashworthiness. By combining multiscale predictive modeling with experimental validation on additively manufactured gyroids, it demonstrates tunable stiffness, collapse stress, and energy absorption.
Mattia Utzeri   +6 more
wiley   +1 more source

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