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Polarizability of atomic Pt, Pt+, and Pt−
The Journal of Chemical Physics, 2021Electrostatic properties are important for understanding and modeling many phenomena, such as the adsorption of a catalytic metal upon an oxide support. The charge transfer between the metal and the support can lead to positive or negative charges on the metal.
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Pt···Pt vs Pt···S Contacts Between Pt-Containing Heterobimetallic Lantern Complexes
Inorganic Chemistry, 2013A trio of Pt-based heterobimetallic lantern complexes of the form [(py)PtM(SAc)4(py)] (M = Co, 1; Ni, 2; Zn, 3) with unusual octahedral coordination of Pt(II) was prepared from a reaction of [PtM(SAc)4] with excess pyridine. These dipyridine lantern complexes could be converted to monopyridine derivatives with gentle heat to give the series [PtM(SAc)4 ...
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