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Pt‐Quantum‐Dot‐Modified Sulfur‐Doped NiFe Layered Double Hydroxide for High‐Current‐Density Alkaline Water Splitting at Industrial Temperature

Advances in Materials, 2023
Suitable electrocatalysts for industrial water splitting can veritably promote practical hydrogen applications. Rational surface design is exceptionally significant for electrocatalysts to bridge the gap between fundamental science and industrial ...
Hang Lei   +4 more
semanticscholar   +1 more source

Optimizing Pt-Based Alloy Electrocatalysts for Improved Hydrogen Evolution Performance in Alkaline Electrolytes: A Comprehensive Review.

ACS Nano, 2023
The splitting of water through electrocatalysis offers a sustainable method for the production of hydrogen. In alkaline electrolytes, the lack of protons forces water dissociation to occur before the hydrogen evolution reaction (HER).
Guoliang Gao   +4 more
semanticscholar   +1 more source

Polarizability of atomic Pt, Pt+, and Pt−

The Journal of Chemical Physics, 2021
Electrostatic properties are important for understanding and modeling many phenomena, such as the adsorption of a catalytic metal upon an oxide support. The charge transfer between the metal and the support can lead to positive or negative charges on the metal.
openaire   +2 more sources

Pt Single Atoms Supported on N‐Doped Mesoporous Hollow Carbon Spheres with Enhanced Electrocatalytic H2‐Evolution Activity

Advances in Materials, 2021
The electronic metal–support interaction (EMSI) plays a crucial role in catalysis as it can induce electron transfer between metal and support, modulate the electronic state of the supported metal, and optimize the reduction of intermediate species.
Panyong Kuang   +7 more
semanticscholar   +1 more source

Pt···Pt vs Pt···S Contacts Between Pt-Containing Heterobimetallic Lantern Complexes

Inorganic Chemistry, 2013
A trio of Pt-based heterobimetallic lantern complexes of the form [(py)PtM(SAc)4(py)] (M = Co, 1; Ni, 2; Zn, 3) with unusual octahedral coordination of Pt(II) was prepared from a reaction of [PtM(SAc)4] with excess pyridine. These dipyridine lantern complexes could be converted to monopyridine derivatives with gentle heat to give the series [PtM(SAc)4 ...
Frederick G, Baddour   +6 more
openaire   +2 more sources

Reversed Charge Transfer and Enhanced Hydrogen Spillover in Pt Nanoclusters Anchored on Titanium Oxide with Rich Oxygen Vacancies Boost Hydrogen Evolution Reaction.

Angewandte Chemie, 2021
The catalytic activity of metal clusters is closely related with the support, while the knowledge about the influence of support on the catalytic activity is scarce.
Zhen‐Wei Wei   +5 more
semanticscholar   +1 more source

Strong Metal-Support Interactions between Pt Single Atoms and TiO2.

Angewandte Chemie, 2020
Strong metal-support interaction (SMSI) has gained great attention in heterogeneous catalysis field. However, whether single - atom catalyst can exhibit SMSI remains unknown.
B. Han   +10 more
semanticscholar   +1 more source

Energetics of Pt adsorption on Pt(111)

Physical Review B, 1994
First-principles local-density-functional (FP-LDF) and embedded-atom-method (EAM) total energies, for a single Pt atom adsorbed on Pt(111), are compared to each other and to field-ion-microscope (FIM) observations. Our EAM calculations predict a small barrier to diffusion and only a slight energy difference between adsorption in the fcc and hcp ...
, Feibelman, , Nelson, , Kellogg
openaire   +2 more sources

Adjacent Atomic Pt Site Enables Single-Atom Iron with High Oxygen Reduction Reaction Performance.

Angewandte Chemie, 2021
Modulation effect has been widely investigated to tune the electronic state of single-atomic M-N-C catalysts to enhance the activity of oxygen reduction reaction (ORR).
Ali Han   +12 more
semanticscholar   +1 more source

Crystalline Lattice‐Confined Atomic Pt in Metal Carbides to Match Electronic Structures and Hydrogen Evolution Behaviors of Platinum

Advances in Materials, 2022
Platinum‐based catalysts occupy a pivotal position in diverse catalytic applications in hydrogen chemistry and electrochemistry, for instance, the hydrogen evolution reactions (HER).
Tian Ma   +12 more
semanticscholar   +1 more source

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