Results 161 to 170 of about 7,201 (251)

Thermally Distinguishable Polyhedral Shapes in Chemistry: 6- and 7‑Coordination. [PDF]

open access: yesACS Omega
Munguba GHL   +4 more
europepmc   +1 more source

Enabling Cross‐Coupling Reactivity of α‐Pentafluorosulfanyl Compounds with a Thermally Stable Organozinc α‐SF5 Reagent

open access: yesChemistry – A European Journal, EarlyView.
This work describes the first example of a thermally stable α‐SF5 organometallic reagent, which allows for extensive downstream functionalization by allylation and acylation reactions under copper catalysis, as well as palladium‐catalyzed Negishi‐type cross‐coupling conditions up to 96% yield. In silico analysis shines initial light on the requirements
Lujie Xu, David Rombach
wiley   +1 more source

Synthesis and Reduction of Super‐Bulky Bis(anilido)acridanide Aluminium Complexes

open access: yesChemistry – A European Journal, EarlyView.
A new generation of super‐bulky bis(anilido)acridanide ligands has been developed and used in the preparation of aluminium(III) complexes. ABSTRACT Super‐bulky bis(anilido)acridanide pro‐ligands (NNNAr)H3 (NNNAr = 4,5‐bis(anilido)‐2,7,9,9‐tetramethylacridanide, anilido = NAr, Ar = DCHP, 2,6‐dicyclohexylphenyl; TCHP, 2,4,6‐tricyclohexylphenyl) have been
Matthew J. Evans   +2 more
wiley   +1 more source

A Review of Grain Boundaries: Formation Mechanism, Synthesis Strategy, and Application in Electrocatalysis

open access: yesEcoEnergy, EarlyView.
An overview of grain boundary engineering in the field of electrocatalysis. ABSTRACT Key electrocatalytic reactions such as HER, OER, ORR, CO2RR, and NRR offer promising routes for storing renewable energy as chemical fuels. However, their widespread application is constrained due to the lack of highly active and stable catalysts. Grain boundaries (GBs)
Jingyu Gao   +8 more
wiley   +1 more source

FEA-guided co-design of bubble microneedles: controlled tip separation for rapid transdermal and sublingual delivery. [PDF]

open access: yesDrug Deliv
Jiang C   +10 more
europepmc   +1 more source

Recent Advances in Pickering Emulsion Templated Phase Change Material Microcapsules: Design, Fabrication, and Multifunctional Applications

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Fabrication process of phase change microcapsules using a Pickering emulsion template method and their subsequent applications. The increasing demand for efficient thermal energy storage systems has driven the development of phase change material microcapsules (PCMMs), which provide high energy‐storage density, reversible phase change, and reduced ...
Ziyan Li   +4 more
wiley   +1 more source

A New High‐Pressure Polymorph of MgTe2O5 with a Unique Crystal Structure

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
MgTe2O5 synthesized under special high‐pressure/high‐temperature conditions of 8 GPa and 800 °C exhibits a unique crystal structure consisting of fused sechser rings built from pseudooctahedral [TeO5]6– and trigonal‐pyramidal [TeO3]2– units. The single‐crystal structure and temperature‐dependent powder diffraction data are presented.
Benjamin J. Pullicino, Gunter Heymann
wiley   +1 more source

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