Results 91 to 100 of about 40,605 (259)

Mechanistic Insights Into Sustainable Catalytic Pyrolysis of Biomass‐Derived Ferulic Acid: The Role of Alumina Regeneration

Chemistry – A European Journal, EarlyView.
Surface‐bound ferulate phenolate complexes undergo styrene‐like polymerization on alumina, yielding a polymeric carbonaceous layer that progressively transforms into polyaromatic carbon domains with concomitant release of aromatic products, while parallel surface‐assisted decarboxylation produces 4‐vinylguaiacol. ABSTRACT A fundamental understanding of
Tetiana V. Kulik, Borys B. Palianytsia, Mykola M. Ilchenko, Nataliia S. Nastasiienko, David J. Morgan, Liudmila P. Storozhuk, David J. Willock, Greg Shaw, Duncan F. Wass, Rafael Luque, Philip R. Davies, Mykola T. Kartel   +11 more
wiley   +1 more source

Pyrene-Derived Covalent Organic Framework Films: Advancements in Acid Vapor Detection

Chemosensors
The expansion of global industry results in the release of harmful volatile acid vapors into the environment, posing a threat to various lifeforms. Hence, it is crucial to prioritize the development of swift sensing systems capable of monitoring these ...
Shaikha S. AlNeyadi, Mohammed T. Alhassani, Ali S. Aleissaee, Ibrahim AlMujaini   +3 more
doaj   +1 more source

Conformational dynamics of the pyrene excimer

Physical Chemistry Chemical Physics
We characterized the S 1 state PES of the pyrene dimer, revealing key excimer conformations. A rapid shift to a stacked-twisted form dominates the excimer's structure and fluorescence.
Giovanni Parolin, Bidhan Chandra Garain, Saikat Mukherjee, Giovanni Granucci, Stefano Corni, Mario Barbatti   +5 more
openaire   +4 more sources

Benzo[c][1,2,5]Thiadiazole Linkers Enhance the Effectiveness of Cavity‐Containing Supramolecular Photocatalysts

Chemistry – A European Journal, EarlyView.
Seven novel supramolecular photosensitizers based on benzo[c][1,2,5]thiadiazole (BTZ) tethered to calix[4]arene (C[4]) scaffolds are reported with facile, scalable, and selective syntheses. Their abilities to produce singlet oxygen have been tested through the photo‐oxidation of α‐terpinene.
Leonardo Amicosante, Dominic Taylor, Cameron L. Campbell, Daniel M. Lambden, Georgina M. Rosair, Filipe Vilela, Scott J. Dalgarno   +6 more
wiley   +1 more source

β‐Ketonitrile‐Modified Prodan Derivatives as Large‐Stokes‐Shift Solvatochromic Fluorophores With Enhanced Brightness and Ratiometric Thermometric Response

Chemistry – A European Journal, EarlyView.
We report a systematic study of β‐ketonitrile–modified Prodan‐type solvatochromic fluorophores. The β‐ketonitrile substitution induces marked bathochromic shifts in absorption and emission and significantly enhances fluorescence quantum yields in nonpolar solvents.
Hiroaki Asakawa, Takuya Tanaka, Kensei Konishi, Gen‐ichi Konishi   +3 more
wiley   +1 more source

Halogenated Tryptophans Improve Integrin αVβ6 Affinity of Cyclic RGD Peptides and Provide Handles for Late‐Stage Derivatization

Chemistry – A European Journal, EarlyView.
Lighting up αVβ6: Halotryptophan engineering converts an RGD scaffold into a modular αVβ6 ligand platform, enabling picomolar affinity and late‐stage functionalization. The resulting probes combine high selectivity with fluorescence for FACS and tumor imaging.
Beate Nachtigall, Caroline Brinkmann, Jana Langosch, Anke Nieß, Norbert Sewald   +4 more
wiley   +1 more source

Nano MIPs (Molecularly Imprinted Polymers) Prepared From a “Frustrated” Gold Nanoparticle‐Based Pre‐Imprinting Matrix: Enhancing Binding Affinity and Selectivity

Chemistry – A European Journal, EarlyView.
A comparative study across ligand‐stabilized gold nanoparticles and surfactant micelles reveals that molecular imprinting strongly depends on the nanoplatform used for imprinting. “Frustrated” noncovalent interactions within the monolayer on gold nanoparticle surface can be exploited to improve both the binding affinity and selectivity for ...
Mansi Sharma, Dashaunette D. Wallace, Yan Zhao   +2 more
wiley   +1 more source

Tribenzotriquinacene Fused Dimers (“Fusodimers”)—Synthesis and Host–Guest Properties

Chemistry – A European Journal, EarlyView.
Two tribenzotriquinacene units merged with each other in either syn‐ or anti‐orientation of the bowls have become accessible in a short synthesis. In contrast to the anti‐isomer, the syn‐isomer forms 1:1 host–guest complexes with both C60 and C70 in solution and in the solid state, as shown by 1H NMR spectroscopy and x‐ray diffraction.
Chun‐Fai Ng, Lisi He, Yin‐Ying Cheung, Xiao‐Ping Cao, Dietmar Kuck, Hak‐Fun Chow   +5 more
wiley   +1 more source

Proximal Steric Shielding Unlocks High Solid‐State Luminescence in Quinoxaline‐Fused Pyrene Heteroacenes

Chemistry – A European Journal, EarlyView.
Proximal steric tuning of quinoxaline‐fused pyrene heteroacenes enables soluble derivatives that exhibit solid‐state photoluminescence quantum yields (PLQYs) up to 82%, surpassing previous benchmarks. This work reveals key structure–property relationships for next‐generation, processable organic emitters in advanced optoelectronic applications ...
Rafiq Ahamed, Sonal Patil, Madhusudan Dutta, Godi Kiran Venkata Sai, Sergey Fisher, Anil Bhadke, Rama Krishna Gamidi, Susnata Pramanik, Tomáš Šolomek, Sudhakar Gaikwad   +9 more
wiley   +1 more source

The Influence of Drosophila Spire and Myosin V During Mid‐Oogenesis Is Independent of Their Direct Interaction

Cytoskeleton, EarlyView.
ABSTRACT Cooperativity between cytoskeletal proteins is crucial for spatiotemporal coordination in biological processes, like oogenesis. In mammalian and Drosophila oogenesis, proper assembly and function of actin networks require coordination between actin assembly factors Spire and formins, as well as actin‐associated proteins like myosins and Rab ...
Joseph Y. Ong, Hannah M. Bailey, Emma Carley, Michelle Panzica, Merin Rixen, Neil Billington, Rong Liu, Margot E. Quinlan   +7 more
wiley   +1 more source