Reduced Symmetry Metal–Organic Cage‐to‐Framework Materials
A series of Ag(I) MOFs was synthesised from organic cages of varying structure and symmetry as linkers. Minor variations in the cage linkers were shown to significantly influence the structures of the resulting MOFs. This work represents the first incorporation of reduced symmetry (including chiral), intrinsically porous building blocks into MOFs, and ...
Cameron J. T. Cox +5 more
wiley +2 more sources
Unlocking inverted singlet-triplet gap in alternant hydrocarbons with heteroatoms. [PDF]
Majumdar A, Das S, Ramakrishnan R.
europepmc +1 more source
Analyses of cytochrome P450 1a (CYP1A)‐knockout (KO) Javanese medaka (Oryzias javanicus) revealed that CYP1A is involved in glucose regulation and reproduction. In the KO fish, significant increases in hepatic transcripts of insulin, glucagon, and somatostatin genes, as well as elevated blood glucose, liver mass, and liver triglyceride levels ...
Suhaila Rusni +10 more
wiley +1 more source
A Ln-MOF Sensor Based on Dual-Signal Response and Logic Gating for the Ratio Fluorescence Detection of Anthrax Biomarkers. [PDF]
Zhang Y, Hou X, Deng W, Wang Z, Zheng Q.
europepmc +1 more source
Pt/C‐Catalyzed Deuteration of Polycyclic Aromatic Hydrocarbons with Suppressed Arene Hydrogenation
An additive‐enabled Pt/C protocol promotes hydrogen–deuterium exchange in fused polycyclic aromatic hydrocarbons (PAHs) in D2O/2‐PrOH at 80 °C. Decalin suppresses undesired ring hydrogenation while accelerating on‐ring H–D exchange, furnishing highly deuterated PAHs (PAHs‐dn).
Naoya Sakurada +6 more
wiley +1 more source
Fluorescence Detection of Pyrene-Stained <i>Bacillus amyloliquefaciens</i> MHR24 in Tomato (<i>Solanum lycopersicum</i> L.) Stem Tissues. [PDF]
Hernández-Rodríguez M +6 more
europepmc +1 more source
Molecular Carrier-Assisted Self-Assembly of <i>st</i>-PMMA Helical Complexes for Fluorescence Sensing of Nitroaromatics in Aqueous Medium. [PDF]
Wang YH, Tseng WT, Wu KY.
europepmc +1 more source
A new method has been developed for the C–H formylation of aromatic compounds using silyl formates synthesized from CO2 and hydrosilanes. This is the first report on the direct C–H formylation of aromatics with silyl formates. The formylation reactions were promoted by BBr3 or BCl3. The reaction mechanism has been clarified by DFT calculations. Despite
Natsumi Nitta +5 more
wiley +1 more source
A methoxy‐functionalized pyrene‐based covalent organic framework (Py‐OCH3‐COF) enables efficient photoelectrocatalytic (PEC) degradation of tetracycline (TC) under neutral conditions. PEC synergy promotes charge separation, reshapes reactive oxygen species, and generates singlet oxygen as the dominant species, leading to rapid and effective TC ...
Zhiying He +6 more
wiley +1 more source
Targeted and Non-Targeted Screening of Organic Pollutants in Atmospheric Aerosols of Arctic Urban Agglomeration Using TD-GC-Orbitrap MS. [PDF]
Shavrina IS +4 more
europepmc +1 more source

