Results 171 to 180 of about 139,650 (284)

Hydrogen Isotope Exchange in Pyridine Catalyzed by an Iron(II) Imido Complex: Counterion‐Directed Regioselectivity

open access: yesAngewandte Chemie, EarlyView.
Anionic high‐spin iron(II) imido complexes are catalysts for the hydrogen isotope exchange (HIE) reaction with pyridine as the substrate. The alkali metal counter‐cation plays critical roles in activating the substrate and facilitating deuteration. These complexes catalyze site‐selective α‐, α,β,γ‐, and β,γ‐deuteration of pyridine, where the counter ...
Bin Feng   +6 more
wiley   +2 more sources

Bent N‐Heterocyclic Allenes From a Well‐Defined Titanium Vinylidene Complex

open access: yesAngewandte Chemie, EarlyView.
The syntheses and the structures of N‐heterocyclic allenes are reported. Allenes bearing fluorenylidene capping groups show markedly bent C═C═C units, a carbene‐like reactivity, and they can act as potent C‐donor ligands for metal complexes. ABSTRACT Allenes typically display a linear geometry. A notable exception occurs in allenes bearing two electron‐
Bastiaan Kooij   +4 more
wiley   +2 more sources

Development of New Pyrazolo [3,4-<i>b</i>]Pyridine Derivatives as Potent Anti-Leukemic Agents and Topoisomerase IIα Inhibitors with Broad-Spectrum Cytotoxicity. [PDF]

open access: yesPharmaceuticals (Basel)
Eldehna WM   +12 more
europepmc   +1 more source

Porous Phenazine‐bridged Tetraoxa[8]Circulenes for Selective Gold Recovery and Heterogeneous Catalysis

open access: yesAngewandte Chemie, EarlyView.
Gold recycling from electronic waste using porous materials is an emerging concept to reduce the environmental impact of gold mining. In this work, we report the synthesis of a highly porous phenazine‐derived tetraoxa[8]circulene polymer and its utilization in gold capture and heterogeneous catalysis.
Patrick W. Fritz   +4 more
wiley   +2 more sources

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