Pyridinium halide promoted ring-opening reactions of exo-norbornene oxide
Ring opening of 1 with pyridinium chloride or pyridinium iodide in chloroform and/or pyridine gives significant amounts of halohydrins 2a or 2b, reflecting partial suppression of the Wagner-Meerwein rearrangement that occurs on ring-opening with hydrogen
G. Gargaro +3 more
core
Multivalent-Anion-Induced Inversion of Chiroptical Signals in a Cyanine Dye Bound to Nanotubular Supramolecular Assemblies. [PDF]
Otsuki M, Hano N, Ihara H, Takafuji M.
europepmc +1 more source
Pyridinium Design for Deaminative Reactions of Sterically Encumbered Alkyl Amines. [PDF]
Enudi OC +5 more
europepmc +1 more source
Hyperpolarization of Pyridine 15N‐Oxide Molecular Probes Enabled by Parahydrogen
Pyridine 15N‐oxides are introduced as motifs for hyperpolarization studies and biochemical applications are demonstrated. ABSTRACT Magnetic resonance (MR) is a powerful non‐invasive technique for probing structural, functional, and metabolic processes with high spatial and temporal resolution.
Ruhuai Mei +8 more
wiley +2 more sources
Metal-Free Active Template: A Straightforward Route to 4-Aminopyridinium-Based Rotaxane Molecular Shuttles. [PDF]
Stoyanov I, van der Lee A, Coutrot F.
europepmc +1 more source
Expanding the Scope of 1,2‐Diazepines Through Alternative Activation Strategies
Often overlooked due to tedious synthetic routes, 1,2‐diazepines can be found in handful of biorelevant molecules. Previous reports from our group lifted the principal synthetic lock: a rapid and user‐friendly protocol to reach monocyclic 1,2‐diazepines from readily available pyridines and electrophilic activating groups. Herein, we extend the scope of
Alexis Leblais +4 more
wiley +1 more source
We introduce a novel chemical derivatisation strategy for the UV‐activated detection of elusive metabolites. Incorporation of a tocopherol‐active chromophore allows for the detection of tagged analytes as photoionised radical cations, selectively induced by a 266 nm laser.
Sofia R. McGowan +5 more
wiley +2 more sources
Efficient and versatile supramolecular functionalization of polysilicon microchips with cationic amphiphile salts for incorporation of therapeutics. [PDF]
Alea-Reyes ME +4 more
europepmc +1 more source
Mechanochemical upcycling of bio‐ and fossil‐based polyesters with alcohols and amines using MeONa as the catalyst selectively produces synthetically useful diesters and diamides, giving only alcohols as byproducts. This green and efficient protocol is readily scalable and can be transferred to the upcycling of polyester‐based postconsumer waste ...
Divya Jain +5 more
wiley +1 more source
Positional isomerization of pyridine through nitrogen transposition. [PDF]
Choi W, Ju H, Park J, Hong S.
europepmc +1 more source

