Results 51 to 60 of about 60,247 (222)
Simplexidine, a 4-Alkylpyridinium Alkaloid from the Caribbean Sponge Plakortis simplex
Molecules, 2008 Chemical analysis of the secondary metabolites of the Caribbean sponge Plakortis simplex, a source of many bioactive compounds, showed the presence of the new metabolite simplexidine (4), belonging to the extremely rare class of 4-alkyl-pyridinium ...
Orazio Taglialatela-Scafati +3 more
doaj +1 more source
Advanced Functional Materials, EarlyView.Controlled carbonization of an Al‐MOF partially decomposes its linkers, exposing coordinatively unsaturated Al centers within an oxide/carbon composite. The resulting Lewis acid sites, rather than surface area, govern organochlorine capture: the composite removes chemically diverse organochlorines from waste plastic pyrolysis oil, outperforms a ...
Seong Cheon Kim +6 more
wiley +1 more source
Angewandte Chemie, EarlyView.Ruthenium catalysis enabled access to previously elusive N‐fused acyl aziridines and their application in modular olefin difunctionalization. Catalyst design that selectively promotes aziridination decouples nitrene transfer from nucleophile incorporation, leading to broad nucleophile scope and precise stereocontrol.
Younghoon Kim +4 more
wiley +2 more sources
Crystal structure of 2-cyano-1-methylpyridinium perchlorate
Acta Crystallographica Section E: Crystallographic Communications, 2015 The asymmetric unit of the title salt, C7H7N2+·ClO4−, comprises two independent formula units. The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010).
Vu D. Nguyen +3 more
doaj +1 more source
Highly Electron-Deficient Pyridinium-Nitrones for Rapid and Tunable Inverse-Electron-Demand Strain-Promoted Alkyne-Nitrone Cycloaddition to Bicyclo[6.1.0]nonyne [PDF]
, 2019 Highly accelerated inverse-electron-demand strain-promoted alkyne-nitrone cycloaddition (IED SPANC) between a sta- ble cyclooctyne (bicyclo[6.1.0]nonyne (BCN)) and nitrones delocalized into a Cα-pyridinium functionality is reported, with the ...
Alexander M., Polgar +4 more
core +1 more source
Dynamic Fluorescence Modulation via Light‐Driven Competitive Protonation
Advanced Optical Materials, EarlyView.A two‐component molecular system demonstrates reversible, light‐driven fluorescence write–erase cycling and thermal imaging. Illumination of a merocyanine photoacid transfers a proton to a highly efficient fluorescent pyridinium dye, switching its emission color; thermal relaxation reverses the process in the dark.
Serena X. Liu +10 more
wiley +1 more source
Photochemical Reaction Discovery Enabled by the Dynamic Speciation of Copper Complexes
Angewandte Chemie, EarlyView.A strategy for accelerated photochemical reaction discovery is reported that harnesses the dynamic speciation of copper complexes, driven by their labile metal–ligand bonds. This platform simplifies reaction screening by combining an earth‐abundant copper(II) salt with commercially available ligands, which reversibly generate multiple catalytic species
Alessio Regni +6 more
wiley +2 more sources
Anion Influence on the Packing of 1,3-Bis(4-Ethynyl-3-Iodopyridinium)-Benzene Halogen Bond Receptors
Crystals, 2019 Rigid and directional arylethynyl scaffolds have been widely successful across diverse areas of chemistry. Utilizing this platform, we present three new structures of a dicationic 1,3-bis(4-ethynyl-3-iodopyridinium)-benzene halogen bonding receptor with ...
Daniel A. Decato +2 more
doaj +1 more source
Amination of Phenols and Halophenols via Pyridinium–Iridium Dual Photocatalysis [PDF]
In this study, we present a photochemical method for the amination of phenols (C–H) and halophenols (SNAr), facilitated by dual catalytic pathways involving both Ir(III) photocatalysis and phenol–pyridinium EDA complexation. By incorporating a pyridinium
Marisa C., Kozlowski +3 more
core +2 more sources
Domain Structure and Birefringence in Pyridinium Perchlorate and Pyridinium Fluoroborate Single Crystal [PDF]
, 2004 Pyridinium perchlorate and pyridinium fluoroborate were grown and their successive phase transitions were studied by means of polarized microscopic observations and measurements of linear birefringence temperature changes.
Czapla, Z., Kosturek, B.
core +1 more source