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Isolable Pyridinium Trifluoromethoxide Salt for Nucleophilic Trifluoromethoxylation
Organic Letters, 2021An isolable pyridinium trifluoromethoxide salt is prepared from the reaction of 4-dimethylaminopyridine with the commercially available liquid 2,4-dinitro(trifluoromethoxy)benzene. The salt is an effective trifluoromethoxide source for SN2 reactions to form trifluoromethyl ethers.
Geraldo Duran-Camacho +4 more
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N-(?-ferrocenylalkyl) pyridinium salts
Bulletin of the Academy of Sciences, USSR Division of Chemical Science, 19661. N- (α-Ferrocenylalkyl)pyridinium p-toluenesulfonates are formed when ferrocenylcarbinols are reacted with p-toluenesulfonyl chloride in pyridine. 2. The N-(α-ferrocenylalkyl)pyridinium salts are good ferrocenylalkylating agents.
A. N. Nesmeyanov +2 more
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Antimycobacterial Activity of Quaternary Pyridinium Salts and Pyridinium N-oxides - Review
Current Pharmaceutical Design, 2012The treatment of tuberculosis and other mycobacterioses is still a major world health problem and new antimycobacterial compounds unrelated to approved drugs are in demand. Quaternary ammonium salts have revealed many usable properties especially as antimicrobials; they are widely used as disinfection and antiseptic agents.
Martin, Krátký, Jarmila, Vinšová
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Direct C–H Sulfonylimination of Pyridinium Salts
Organic Letters, 2022A direct pyridinium C-H sulfonylimination has been developed for the synthesis of sulfonyl iminopyridine derivatives with high efficiency. This transformation features the direct and efficient formation of a C═N bond with a high functional group tolerance under metal-free conditions.
Lihua Luo +8 more
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Recyclization of polysubstituted pyridinium salts
Tetrahedron, 1995Abstract 3,5-Diacetyl- and 3,5-dicyano-1,2,6-trimethylpvridinium perchlorates are converted by recyclization into N,5-dimethylanilines and 2-methylaminopyridines, respectively.
Galina P. Shkil +3 more
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Rapid Electrophilic Cysteine Arylation with Pyridinium Salts
Bioconjugate Chemistry, 2022Here, we present a series of fluorinated cationic reagents that enable rapid arylation of cysteine under mild conditions compatible with proteins and peptides. The highly polarized C-F bond and attractive nucleophile-electrophile Coulombic interactions substantially accelerate cysteine arylation, leading to unusually high rate constants on the order of
Bradley M. Lipka +9 more
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Hexahydrobenzothiazolo[3,2-a]pyridinium salts
Chemistry of Heterocyclic Compounds, 1988Salts of hexahydrobenzothiazolo[3,2-a]pyridine are obtained by exchange reactions. Anions are placed in the order [(NC)2CCHC(CN)2]- > ClO4−>I3−>Br− according to the ability to displace each other. X-ray structural and spectroscopic studies establish the cis-attachment of the thiazolidine and cyclohexane rings in the hexahydrobenzothiazolo [3,2-a ...
A. M. Shestopalov +6 more
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Catalytic hydrogenation of pyridinium salts
Chemistry of Heterocyclic Compounds, 1994Catalytic hydrogenation of polysubstituted pyridinium salts leads to piperidines and their condensed analogs The spatial properties and conformational properties of the saturated azaheterocycles have been determined by13C NMR spectorscopy. It was shown that hydrogenation of the pyridinium salts occurs stereoselectively to form cis isomers in most cases.
P. V. Reshetov +2 more
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New electrochromic polymeric pyridinium salts
Polymer Science Series B, 2009A series of new anode-cathode conjugated electrochromic polymeric pyridinium salts containing mainchain triphenylamine units and demonstrating multicolor electrochromism has been synthesized. All of the polymers exhibit intense UV absorption with maxima of absorption and fluorescence at 340–343 and 336–338 nm in DMF solutions and 460–461 and 410–438 nm
M. L. Keshtov +2 more
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