Results 131 to 140 of about 1,007,161 (276)
Boosting Reversible Photocontrol of a Photoxenase by an Engineered Conformational Shift
Angewandte Chemie, EarlyView.Photocontrol of enzymes with photoswitchable unnatural amino acids hitherto yielded only limited light‐regulation factors (LRFs). Here we boosted the LRF of an imidazole glycerol phosphate synthase variant from ∼15 to ∼100 in a semi‐rational design approach and unraveled the mechanistic fundamentals of this effect via biophysical and computational ...
Sabrina Mandl +6 more
wiley +2 more sources
Correction: Critical assessment of copper-alginate hydrogel beads as recyclable and heterogeneous catalysts for aqueous azide‒alkyne cycloaddition. [PDF]
Front ChemMoglie Y +3 more
europepmc +1 more source
Angewandte Chemie, EarlyView.We report a fluoride‐transfer asymmetric allylic alkylation (AAA) in which all reagent atoms, including the leaving group, are incorporated into the products. This atom‐efficient AAA protocol enables the cross‐electrophile coupling of allyl fluorides and gem‐difluoroalkenes, providing a catalyst‐controlled, regiodivergent, and stereoselective access to
Jordi Duran +5 more
wiley +2 more sources
Correction: Two-carbon ring expansion of bicyclic aziridines to oxazocines <i>via</i> aryne insertion into a σ C-N bond. [PDF]
Chem SciRampon DS +7 more
europepmc +1 more source
Angewandte Chemie, EarlyView.Discrete porous metal–organic cages provide a platform to extend porosity beyond crystalline solids. Their peripheral functionality governs inter‐cage interactions and physical state, enabling preservation of intrinsic porosity across liquids, glasses, and rubbers.
Francisco Sánchez‐Férez +2 more
wiley +2 more sources
Novel qNMR Method to Quantify Psilocybin and Psilocin in Psychedelic Mushrooms. [PDF]
ACS OmegaRodríguez L +5 more
europepmc +1 more source