Results 61 to 70 of about 34,775 (190)

Photocatalytic Degradation of Paracetamol in Aqueous Medium Using TiO₂ Prepared by the Sol–Gel Method

Molecules, 2022
Two titania photocatalysts have been prepared using the sol–gel method using TiCl4 as a precursor, and two different alcohols, namely, ethanol or propanol (Et or Pr).
Raquel Trujillano, Vicente Rives, Inés García   +2 more
doaj   +1 more source

Efectos de la erupción del Complejo Volcánico Puyehue-Cordón Caulle (CVPCC) sobre la salud humana y el medio ambiente en distintos sectores de la localidad de Villa la Angostura, Neuquén [PDF]

, 2012
Fil: Canafoglia, María Elena. Centro de Química Inorgánica (CEQUINOR). Facultad de Ciencias Exactas. Universidad Nacional de La Plata; ArgentinaFil: Vasallo, Marta. Centro de Enseñanza Media Nro 17 (CPEM Nro 17). Villa La Angostura. Neuquén; ArgentinaFil:
Barone, Vicente, Botto, Irma Lia, Canafoglia, María Elena, Vasallo, Marta   +3 more
core  

Reversible I2 Uptake Induces Record‐High Spin‐Crossover Hysteresis in a Fe(II) Hofmann‐Type MOF

Chemistry – A European Journal, EarlyView.
Reversible iodine uptake in a flexible Fe(II) Hofmann‐type MOF [Fe(pz)Pd(CN)4] induces record‐wide SCO hysteresis. Gas‐phase I2 acts as internal chemical pressure, stabilizing both high‐spin and LS states without altering the framework, providing a general strategy for tunable bistability in coordination networks.
Mario Pacheco, Higinio Maqueda‐Márquez, Annena Jesuman, Ana Belén Gaspar   +3 more
wiley   +1 more source

Vibrational assignments of two polymorphic forms of metaxolone by using DFT calculations and the SQM methodology [PDF]

, 2018
A theoretical study has been performed on the musclerelaxant 5-[(3, 5-dimethylphenoxy)methyl]-1,3-oxazolidin-2-one, of generic name metaxolone (MTX), by using the hybridB3LYP/6-31G calculations in the gas phase and theexperimental available infrared and ...
Brandan, Silvia Antonia, Iramain, Maximiliano Alberto, Ledesma, Ana Estela, Márquez, María J.   +3 more
core  

Ground‐ and Excited‐State Mixed Valency in a 4,4′‐Bipyridine‐Bridged Bimetallic Di‐Ruthenium Complex

European Journal of Inorganic Chemistry, EarlyView.
Photoinduced mixed‐valence interactions across a 4,4′‐bpy bridge were studied. MLCT excited states in the bimetallic complex are longer‐lived than in the monometallic reference, thanks to metal–metal electronic coupling and hole delocalization, but are still shorter than the nanosecond timescale relevant for diffusional reactivity.
Ivana Ramírez‐Wierzbicki, Frank W. Heinemann, Leonardo D. Slep, Alejandro Cadranel   +3 more
wiley   +1 more source

Unprecedented layered coordination polymers of dithiolene group 10 metals: Magnetic and electrical properties [PDF]

, 2016
One-pot reactions between Ni(ii), Pd(ii) or Pt(ii) salts and 3,6-dichloro-1,2-benzenedithiol (HSC6H2Cl2SH) in KOH medium under argon lead to a series of bis-dithiolene coordination polymers.
Delgado, Esther, Gómez-García, Carlos J., Hernández, Diego, Hernández, Elisa, Martín, Avelino, Zamora, Félix   +5 more
core   +2 more sources

Biofertilization of canola seeds with Peribacillus simplex and Paenibacillus polymyxa bacteria increases tocopherol content

JSFA reports, EarlyView.
Abstract Background Biofertilization with plant growth‐promoting bacteria (PGPB) is a reliable strategy to reduce the amounts of chemical fertilizers applied to crops. Nevertheless, the effects of biofertilizers on plant chemical constituents that influence food quality and human health should be evaluated.
Pilar Martínez‐Hidalgo, José David Flores‐Félix, José M. Igual, Encarna Velázquez, Fernando González‐Andrés, Eustoquio Martínez‐Molina   +5 more
wiley   +1 more source

Smart NIR‐Emitting Organometallo Pt(II)‐Ionosilica Aerogel for Selective Au(III) Sensing and Recovery

Small, EarlyView.
This study reports a near‐infrared emitting ionic aerogel composed of cationic cyclometalated Pt(II) moieties linked by Si─O─Si bonds. The resulting porous hybrid material enables the selective detection and recovery of Au(III) ions from mixed‐metal solutions. Owing to its reversible luminescent response and thiourea‐assisted gold recovery, the aerogel
Janira Herce, Veronica Torregrosa‐Rivero, Elena Serrano, Albertina Cabañas, Miguel Angel Rodríguez, Julio Fernández‐Cestau, Mattia Nieddu, Jesús Rubén Berenguer, Javier García‐Martínez   +8 more
wiley   +1 more source

Metal‐Free Electrophilic Borylative Cyclizations of Alkynes

The Chemical Record, EarlyView.
Metal‐free borylative cyclizations based on electrophilic alkyne activation by boron Lewis acids provide efficient access to borylated hetero‐ and carbocycles. Early studies using B(C6F5)3 displayed limited scope and application, whereas recent ClBcat‐ and BCl3‐based methods enable mild CB and CC/CX bond formation for the synthesis of cycles ...
Jaime Mateos‐Gil, Marcos Humanes, Manuel A. Fernández‐Rodríguez, Patricia García‐García   +3 more
wiley   +1 more source

Stabilization of Zwitterionic Versus Canonical Glycine by DMSO Molecules

Pharmaceuticals
Background/Objectives: Understanding the stabilization mechanisms of amino acid conformations in different solvent environments is crucial for elucidating biomolecular interactions and crystallization processes.
Verónica Martín, Alejandro Colón, Carmen Barrientos, Iker León   +3 more
doaj   +1 more source