Results 61 to 70 of about 22,388 (172)

π‐Enlargement in Porphyrin Macrocycles at Interfaces

open access: yesAngewandte Chemie, Volume 138, Issue 30, 20 July 2026.
On‐surface synthesis of a 20‐π free‐base expanded porphyrin, by depositing onto a hot Ag(111) substrate an 18‐π free‐base precursor equipped with ‐CF3 functional groups ABSTRACT Porphyrins are essential heteroatomic macrocycles, fundamental to both biological systems and advanced technology.
Ana Barragán   +11 more
wiley   +2 more sources

A High‐Performance Oxidized Graphene for Dendrite‐Free Anodes and Kinetically Enhanced Cathodes of Aqueous Zn‐Ion Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Oxidized graphene rich in carboxylic acid groups obtained via a simple electrochemical exfoliation route is shown to tackle the main challenges of aqueous Zn‐ion batteries (AZIBs), specifically short Zn anode cycle life and sluggish cathode reaction kinetics.
Enrique Álvarez‐Rubiera   +9 more
wiley   +1 more source

Nitrogen-Rich Multinuclear Ferrocenophanes as Multichannel Chemosensor Molecules for Transition and Heavy-Metal Cations

open access: yesSensors, 2014
[m.n] Multinuclear ferrocenophanes prepared by aza-Wittig reaction of bisiminophosphoranes derived from 1,1'-diazidoferrocene and isophthaladelhyde or 2,5-diformylthiophene, behave as efficient electrochemical and chromogenic chemosensor molecules for ...
Antonia Sola   +3 more
doaj   +1 more source

Diastereoselective Synthesis of Highly Substituted Methylene Cyclobutanes by Pd Catalysis

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A chemo‐ and diastereoselective palladium‐catalyzed intramolecular coupling/cyclization of borylated 1,5‐dienes, readily accessible by allene allylboration, with iodoarenes enables the synthesis of highly substituted methylene cyclobutanes. The method exhibits broad scope, high functional group tolerance, and complete enantiospecificity.
Jose M. Malga   +1 more
wiley   +1 more source

Nanographene‐Based van der Waals Organic Framework With Permanent Porosity

open access: yesAngewandte Chemie, Volume 138, Issue 27, 1 July 2026.
Unlocking record‐breaking porosity in a supramolecular organic framework (SOF). Through the strategic design of a C3‐symmetric nanographene, a robust supramolecular framework is achieved via exclusively weak van der Waals forces. This metal‐free scaffold reaches a benchmark BET surface area of 1108 m2 g−1 –the highest to date for this class–combining ...
Arturo Oró   +5 more
wiley   +2 more sources

Influence of the cis/trans configuration on the supramolecular aggregation of aryltriazoles

open access: yesBeilstein Journal of Organic Chemistry, 2019
The ability of trans- and cis-1,2-glucopyranosyl and cyclohexyl ditriazoles, synthesized by CuAAC "click" chemistry, to form gels was studied, their physical properties determined, and the self-aggregation behavior investigated by SEM, X-ray, and EDC ...
Sara Tejera   +5 more
doaj   +1 more source

17‐epi‐Melianodiol, a new protolimonoid from Melia azedarach fruits, exhibits larvicidal activity and is associated with oxidative imbalance and midgut epithelial damage in Aedes aegypti larvae

open access: yesPest Management Science, EarlyView.
The bio‐guided phytochemical study resulted in the new compound 17‐epi‐melianodiol. The compound eliminated 100% of Aedes aegypti larvae at 100 ppm, causing pronounced morphological changes, cuticular damage, and extensive vacuolization. Abstract BACKGROUND In Brazil, Aedes aegypti is the primary vector of arboviruses such as dengue, chikungunya ...
Kethleen Duarte Crespo Soares   +8 more
wiley   +1 more source

A Deep‐Red‐Absorbing Osmium(II) Complex as a Photosensitizer for Photodynamic Therapy Inducing Immunogenic Cell Death

open access: yesAngewandte Chemie, Volume 138, Issue 27, 1 July 2026.
A deep‐red‐excited osmium(II) photosensitizer (Os2) induces immunogenic cell death (ICD) under 740 nm irradiation and triggers robust anti‐tumor immune responses both in vitro and in vivo. ABSTRACT Immunogenic cell death (ICD), which converts tumor cells into their own vaccine, plays a pivotal role in the development of novel anticancer therapies. Here,
Yiyi Zhang   +12 more
wiley   +2 more sources

Cytotoxic and Antitumor Activity of some Coumarin Derivatives

open access: yesNatural Product Communications, 2016
Several natural and synthetic coumarins were assayed against different cancer cell lines. Four of them have shown cytotoxicity against a panel of three human solid tumor cell lines (HeLa, T-47D, and WiDr) and a clearly activity/hydrophobicity ...
Hugo A. Garro   +3 more
doaj   +1 more source

Dendrimeric Antigens for Passive Mast Cell Activation in the Evaluation of Amoxicillin Allergy

open access: yesAllergy, EarlyView.
DeAns with defined nanoscale structure reveal that conjugate size and determinant density govern IgE‐mediated effector‐cell activation in AX allergy. All DeAn generations bind to sIgE in inhibition immunoassay, but only larger DeAns trigger FcεRI‐dependent responses in mouse MC, huRBL‐2H3, and LUVA cells.
Amene Tesfaye Ayane   +12 more
wiley   +1 more source

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