Results 121 to 130 of about 190,564 (233)

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Novel Bioactive Multifunctional Polyphenols: A Chemo‐Enzymatic Approach

open access: yesChemistry – A European Journal, EarlyView.
One‐step synthesis of complex alkyl oxystilbenin glucosides (6‐47% yield) in alcoholic medium. Switching to ter‐BuOH as solvent afforded δ‐Viniferin diglucoside, with high selectivity and high yield (> 90%), that can be upgraded by enzymatic esterification to alkyl δ‐Viniferin diglucosides.
Amandine L. Flourat   +8 more
wiley   +1 more source

Induced‐Fit Recognition by a Calixarene–Pyrene Conjugate for Single‐ and Dual‐Wavelength Fluorescence Sensing in Water

open access: yesChemistry – A European Journal, EarlyView.
A sulfonatocalix[4]arene–pyrene conjugate functions as a fluorescence chemosensor for the optical detection of biorelevant analytes in water. Its photoinduced electron transfer (PET) response is triggered by an induced‐fit recognition mechanism. Noncovalent assembly with an additional dye affords dual‐color ratiometric signaling via competitive PET ...
Joana N. Martins   +4 more
wiley   +1 more source

Transient thermal modelling of green anode cooling in the aluminium industry

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Summary of the methodology. Abstract Anodes, which are used in electrolytic aluminium production, are made by mixing dry aggregate (petroleum coke, rejected anodes, and butts) with coal tar pitch, compacting the resulting paste (green anode), and baking (baked anode). After compaction, the anodes are cooled to maintain their structural integrity before
Mohammadhossein Dabaghi   +2 more
wiley   +1 more source

Subuniformity of harmonic mean p$$ p $$‐values

open access: yesCanadian Journal of Statistics, EarlyView.
Abstract We obtain several inequalities on the generalized means of dependent p$$ p $$‐values. In particular, the weighted harmonic mean of p$$ p $$‐values is strictly subuniform under several dependence assumptions of p$$ p $$‐values, including independence, negative upper orthant dependence, the class of extremal mixture copulas, and some Clayton ...
Yuyu Chen   +3 more
wiley   +1 more source

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