Results 81 to 90 of about 6,663 (226)

Description of ultrastrong light–matter interaction through coupled harmonic oscillator models and their connection with cavity-QED Hamiltonians

open access: yesNanophotonics
Classical coupled harmonic oscillator models are capable of describing the optical and infrared response of nanophotonic systems where a cavity photon couples to dipolar matter excitations. The distinct forms of coupling adopted in these classical models
Muniain Unai   +4 more
doaj   +1 more source

Coupled harmonic oscillators and their quantum entanglement [PDF]

open access: yesPhysical Review E, 2018
A system of two coupled quantum harmonic oscillators with the Hamiltonian ${\hat H}=\frac{1}{2}\left(\frac{1}{m_1}{\hat p}^{2}_1 + \frac{1}{m_2}{\hat p}^{2}_2+A x^2_1+B x^2_2+ C x_1 x_2\right)$ can be found in many applications of quantum and nonlinear physics, molecular chemistry, and biophysics. The stationary wave function of such a system is known,
openaire   +3 more sources

Charge Resonance Interaction in Aromatic Trimer Radical Cations Revealed by IR Spectroscopy: The Case of Pyrrole Homo‐ and Heterotrimers

open access: yesChemistry – A European Journal, EarlyView.
We demonstrate the power of high‐resolution infrared spectroscopy and complementary quantum chemical calculations to unravel the evolution of the aromatic charge resonance interaction (CR) in cold trimer radical cations for the prototypical pyrrole clusters.
Dashjargal Arildii, Otto Dopfer
wiley   +1 more source

Homological quantum mechanics

open access: yesJournal of High Energy Physics
We provide a formulation of quantum mechanics based on the cohomology of the Batalin-Vilkovisky (BV) algebra. Focusing on quantum-mechanical systems without gauge symmetry we introduce a homotopy retract from the chain complex of the harmonic oscillator ...
Christoph Chiaffrino   +2 more
doaj   +1 more source

Cyclization of a 1,8‐Diphenylanthracene by Scholl Reactions to Form Five‐ and Seven‐Membered Ring Embedded Polycyclic Aromatic Hydrocarbons

open access: yesChemistry – A European Journal, EarlyView.
Reactions of 10‐mesityl‐1,8‐diphenylanthracene with DDQ/TfOH produced three products via sequential formation of a five‐ or seven‐membered ring. Unexpectedly, the triply cyclized product with a rubicene substructure was formed through cyclization involving 1,2‐methyl shift.
Tatsuhiro Sasaki   +2 more
wiley   +1 more source

Quantum entanglement of a harmonic oscillator with an electromagnetic field [PDF]

open access: yesScientific Reports, 2018
AbstractAt present, there are many methods for obtaining quantum entanglement of particles with an electromagnetic field. Most methods have a low probability of quantum entanglement and not an exact theoretical apparatus based on an approximate solution of the Schrodinger equation.
openaire   +4 more sources

Linear and Two‐Dimensional Infrared Spectroscopy of the Multifunctional Vibrational Probe, 3‐(4‐Azidophenyl) Propiolonitrile. Deperturbing a Fermi Triad by Isotopic Substitution

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Linear infrared spectroscopy combined with isotope labeling and density functional theory unravels the origin of a Fermi triad in a multifunctional vibrational chromophore. Ultrafast 2DIR‐spectroscopy reports directly on the dynamics and the intramolecular vibrational energy flow pathways in the isotopically deperturbed system. Abstract Infrared probes
Claudia Gräve   +4 more
wiley   +1 more source

Anisotropy Factor Spectra for Weakly Allowed Electronic Transitions in Chiral Ketones

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Anisotropy factor spectra for the weak n→π*‐type A‐band of chiral ketones cannot be described within the Franck–Condon approximation. Thus, we present such spectra computed by accounting for Herzberg–Teller corrections and compare them to experiments for fenchone, camphor and 3MCP to describe chiroptical properties of these molecules in the mid to near
Leon A. Kerber   +5 more
wiley   +1 more source

GENERALIZED HEISENBERG RELATION AND QUANTUM HARMONIC OSCILLATORS [PDF]

open access: yesInternational Journal of Modern Physics A, 2006
We study the consequences of the generalized Heisenberg uncertainty relation which admits a minimal uncertainty in length such as the case in a theory of quantum gravity. In particular, the theory of quantum harmonic oscillators arising from such a generalized uncertainty relation is examined.
openaire   +2 more sources

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