Results 21 to 30 of about 4,161,887 (128)
The Preparatory (Anti)Bonding Character of Molecular Orbitals
Herein, a concept to qualitatively predict changes in bond dissociation energies upon reduction or oxidation of molecular compounds is introduced. Changing the population of so‐called preparatory molecular orbitals influences how molecular fragments are relaxing after bond cleavage, which is shown for isolated organometallic aluminum compounds as well ...
Jonas O. Wenzel +10 more
wiley +1 more source
Furrow tillage resolves the conventional‐vs.‐no‐tillage trade‐off by simultaneously cutting CO2 efflux to 2.0–3.0 g C m−2 d−1 and unlocking high nutrient availability for the rice rhizosphere. This scalable agronomic solution strengthens soil health, enhances plant physiology, reshapes microbial metabolism, and shifts paddy systems toward a net ...
Arnab Majumdar +10 more
wiley +1 more source
Interpretive themes in quantum physics : curriculum development and outcomes [PDF]
A common learning goal for modern physics instructors is for students to recognize a difference between the experimental uncertainty of classical physics and the fundamental uncertainty of quantum mechanics.
N. Sanjay Rebello +6 more
core +1 more source
Given the prominence of 19F‐bioNMR in structural research, fluorinated glycans hold enormous potential in glycomimetic frameshift design. However, challenges associated with the stereocontrolled synthesis of these disruptive actors continue to frustrate advances. To address this, the automated synthesis of selectively C‐2 fluorinated glycans related to
James Suri +6 more
wiley +2 more sources
Durch einen strukturbasierten Designansatz wurden photoschaltbare Derivate des von der FDA zugelassenen Arzneistoffes Suvorexant entwickelt, gedockt, synthetisiert und pharmakologisch an den Orexin‐1‐ und 2‐Rezeptoren (OX1R und OX2R) charakterisiert.
Marcus Angermann +10 more
wiley +1 more source
Probability in physics: stochastic, statistical, quantum [PDF]
I review the role of probability in contemporary physics and the origin of probabilistic time asymmetry, beginning with the pre-quantum case (both stochastic mechanics and classical statistical mechanics) but concentrating on quantum theory. I argue that
Wallace, David
core
Following a structure‐based design approach, photoswitchable derivatives of the FDA‐approved drug suvorexant were designed, docked, synthesized, and characterized pharmacologically at the orexin 1 and 2 receptors (OX1R and OX2R). Optimized “photorexant” showed up to an 11‐fold difference in IC50 between photoisomers, enabled dynamic and reversible ...
Marcus Angermann +10 more
wiley +1 more source
Two Dogmas About Quantum Mechanics [PDF]
We argue that the intractable part of the measurement problem -- the 'big' measurement problem -- is a pseudo-problem that depends for its legitimacy on the acceptance of two dogmas.
Itamar Pitowsky +3 more
core
We report a cellular membrane‐targeted europium(III) probe, Eu.Chol, that enables selective, time‐resolved detection of peroxynitrite (ONOO−) at the cell membrane interface. Eu.Chol demonstrates efficient incorporation into liposomes and Jurkat cells, with minimal response to H2O2, establishing a modular platform for subcellular ONOO− sensing ...
Jamie Webb +6 more
wiley +1 more source
From Physics to Information Theory and Back [PDF]
Quantum information theory has given rise to a renewed interest in, and a new perspective on, the old issue of understanding the ways in which quantum mechanics differs from classical mechanics.
Myrvold, Wayne
core

