Results 221 to 230 of about 1,987,784 (294)
Angewandte Chemie, EarlyView.A nanopore composed of transmembrane peptides and a DNA scaffold that assists peptide assembly was constructed. By employing peptides containing the unnatural amino acid 2‐aminoisobutyric acid (Aib), which promotes loose packing between helices, a large‐diameter nanopore was achieved.
Zugui Peng +3 more
wiley +2 more sources
Angewandte Chemie, EarlyView.The Sabatier principle and volcano plots declare that optimal electrocatalysis is found in the middle between strong and weak binding of key intermediates. However, it is shown here that during anion electroreduction, strong and weak binding are potential‐dependent concepts and volcanoes are mobile.
Mattia Salomone +2 more
wiley +2 more sources
Ultra‐Thin and Highly Insulating Aromatic Monolayers by N‐Heterocyclic Carbenes
Angewandte Chemie, EarlyView.By using N‐heterocyclic carbenes extremally insulating and at the same time as thin as 0.3 nm molecular films are formed. The charge transport calculations indicate absence of destructive quantum interference effect which was so far the only way to suppress conductivity in aromatic molecules.
Mateusz Wróbel +6 more
wiley +2 more sources
Angewandte Chemie, EarlyView.Molecular recognition guest binding can comprehensively modulate photoinduced charge‐transfer dynamics in the cyclophane host, including charge separation and recombination, via coherent superexchange and incoherent hopping. Unlike covalent donor–bridge–acceptor systems, this supramolecular approach avoids tedious syntheses and offers precise tuning of
Xueze Zhao +11 more
wiley +2 more sources
Unlocking a Nitrosuccinate Lyase for Decarboxylative Enzymatic Hydronitration
Angewandte Chemie, EarlyView.The nitrosuccinate lyase CreD catalyzes C–NO2 bond formation using nitrite in water and shows synthetic practicality with high turnover numbers up to 102,000. A combination of protein engineering and computational methods helped to reveal the mechanistic principles that underpin this unique enzymatic activity.
Matteo Aleotti +9 more
wiley +2 more sources
Angewandte Chemie International Edition, EarlyView.Electroenzymatic CO2 fixation enables energy‐efficient, highly selective synthesis of complex molecules. Unlocking its full potential requires fundamental understanding of electrode‐coupled reductases and carboxylases. This review critically discusses available enzymes, product scope, and key thermodynamic and kinetic considerations, highlighting ...
Leonardo Castañeda‐Losada +4 more
wiley +1 more source
A Triple-well resonant tunneling diode for multiple-valued logic application
, 1988 Mizuta, Hiroshi +2 more
core
A new triple-well resonant tunneling diode with controllable double-negative resistance
, 1988 Mizuta, Hiroshi +2 more
core
Linking Synthetic Materials Chemistry to Electrocatalytic Performance
Angewandte Chemie International Edition, EarlyView.Synthetic materials chemistry governs electrocatalyst performance through precise control of phase, composition, defects, and morphology, while emerging operando techniques, data‐driven approaches, and automated laboratories are advancing the field toward predictive catalyst design for sustainable energy conversion.
Debabrata Bagchi +3 more
wiley +1 more source