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Kirkendall‐Effect‐Mediated Hollow Bimetallic Hexacyanoferrates for Aqueous Zn‐Ion Batteries: Suppressing Jahn–Teller Distortions and Enhancing Ion Transport and Cyclability

open access: yesCarbon Energy, EarlyView.
Kirkendall‐engineered hollow Ni–Mn hexacyanoferrates feature Ni‐tunable shell thickness and uniform alloying, coupling architectural control with electronic stabilization. Composition–morphology co‐optimization suppresses Mn³⁺‐driven Jahn–Teller distortions and lowers charge‐transfer barriers, enabling rapid Zn²⁺ transport and reversible redox.
Jihong Kim   +12 more
wiley   +1 more source

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