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Catalysis of Radical Reactions: A Radical Chemistry Perspective
Angewandte Chemie - International Edition, 2016The area of catalysis of radical reactions has recently flourished. Various reaction conditions have been discovered and explained in terms of catalytic cycles. These cycles rarely stand alone as unique paths from substrates to products.
Armido Studer, Dennis P Curran
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A radical approach to radicals
Acta Crystallographica Section D Structural Biology, 2022Nitroxide radicals are characterized by a long-lived spin-unpaired electronic ground state and are strongly sensitive to their chemical surroundings. Combined with electron paramagnetic resonance spectroscopy, these electronic features have led to the widespread application of nitroxide derivatives as spin labels for use in studying protein structure ...
Youjia Liu +2 more
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Environmental Science and Technology, 2022
Single-atom catalysts (SACs)-based peroxymonosulfate (PMS) systems are highly selective to the type of organic pollutants while the mechanisms remain ambiguous.
Mengxue Yang +8 more
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Single-atom catalysts (SACs)-based peroxymonosulfate (PMS) systems are highly selective to the type of organic pollutants while the mechanisms remain ambiguous.
Mengxue Yang +8 more
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Phosphorus radicals and radical ions
Dalton Transactions, 2022This review presents the so far isolated and structurally characterized phosphorus-centered radicals and radical ions. Their reactivity, structure, and bonding are described.
Bindusagar Das +2 more
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Aging: a theory based on free radical and radiation chemistry.
Journal of Gerontology, 1956The phenomenon of growth, decline and death—aging—has been the source of considerable speculation (1, 8, 10). This cycle seems to be a more or less direct function of the metabolic rate and this in turn depends on the species (animal or plant) on which ...
D. Harman
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Commentary: When is a Radical not a Radical?
Free Radical Research, 1996It is not commonly realised that symmetrical Fe(III) complexes are expected to have EPR spectra dominated by a symmetrical narrow line close to the free-spin g-value. The aim of this note is to stress that such features can be mistakenly identified as the spectra for stable organic radicals.
Declan P. Naughton, Martyn C. R. Symons
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Hegemony and Socialist Strategy: Towards a Radical Democratic Politics
, 1988In this hugely influential book, Laclau and Mouffe examine the workings of hegemony and contemporary social struggles, and their significance for democratic theory.
E. Laclau, C. Mouffe
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The free radical theory of aging matures.
Physiological Reviews, 1998The free radical theory of aging, conceived in 1956, has turned 40 and is rapidly attracting the interest of the mainstream of biological research.
K. Beckman, B. Ames
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Terrorism, radicalization and de-radicalization
Current Opinion in Psychology, 2016In this article, we review the literature and present a model of radicalization and de-radicalization. In this model, we distinguish three phases in radicalization: (1) a sensitivity phase, (2) a group membership phase and (3) an action phase. We describe the micro-level, meso-level and macro-level factors that influence the radicalization process in ...
Doosje, B. +5 more
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Superoxide radical and superoxide dismutases.
Annual Review of Biochemistry, 1995O2- oxidizes the [4Fe-4S] clusters of dehydratases, such as aconitase, causing-inactivation and release of Fe(II), which may then reduce H2O2 to OH- +OH.. SODs inhibit such HO.
I. Fridovich
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