Non-steady scaling model for the kinetics of the photo-induced free radical polymerization of crosslinking networks [PDF]
Recently, a semi-empirical scaling model was introduced to account for the free-radical polymerization kinetics of acrylated urethane precursors in the solid-state.
Roose, Patrice +2 more
core +2 more sources
"Research progress in preparation of thermoplastic elastomers by living controlled polymerization"
Starting with polymerization methods such as anionic polymerization, cationic polymerization, ring-opening polymerization, and controlled free radical polymerization, the research progress of different types of thermoplastic elastomer synthesis ...
ZHANG hao1, ZHANG Hua-qiang2, LIU Ruo-fan1, ZHAO Zhi-chao2, JIN Yu-shun1, LI Fu-chong2, WU Yi-bo1
doaj +1 more source
It is the chain growth specific reaction rate that was determined for the process of methyl methacrylate mass radical polymerization within the temperature range of 40–900 С in quasi-steady approximation by means of Monte Carlo method.
A. A. Sultanova +2 more
doaj +1 more source
A supramolecular radical cation: folding-enhanced electrostatic effect for promoting radical-mediated oxidation. [PDF]
We report a supramolecular strategy to promote radical-mediated Fenton oxidation by the rational design of a folded host-guest complex based on cucurbit[8]uril (CB[8]). In the supramolecular complex between CB[8] and a derivative of 1,4-diketopyrrolo[3,4-
Jiao, Yang +7 more
core +2 more sources
Recent Applications of the (TMS)3SiH Radical-Based Reagent
This review article focuses on the recent applications of tris(trimethylsilyl)silane as a radical-based reagent in organic chemistry. Numerous examples of the successful use of (TMS)3SiH in radical reductions, hydrosilylation and consecutive radical ...
Chryssostomos Chatgilialoglu +1 more
doaj +1 more source
Modern methods of controlled radical polymerization for obtaining branched polymers of acrylamide, acrylic acid and (met)acrylates [PDF]
A search and analysis has been carried out of English-language 2005–2020 scientifi c literature devoted to methods of obtaining branched (co)polymers of acrylamide, acrylic acid and (met)acrylates in order to obtain novel materials with ...
Bayburdov, Telman А. +1 more
doaj +1 more source
Synthesis and Characterization of Poly(vinyl acetate)-b-poly(dimethylsiloxane) Diblock Copolymer by Iodine Transfer Radical Polymerization [PDF]
Iodine transfer radical polymerization as an easy, efficient and robust method of controlled radical polymerization has been applied for a wide range of monomers.
Mojtaba Farrokhi +2 more
doaj +1 more source
Intrazeolite assembly and pyrolysis of polyacrylonitrile [PDF]
Radical polymerization of acrylonitrile within the pores of zeolites Y and mordenite produces intrazeolite polyacrylonitrile that can be pyrolysed to form conducting carbon ...
Bein, Thomas +2 more
core +1 more source
Radical Polymerization of Alkyl 2-Cyanoacrylates
Cyanoacrylates (CAs) are well-known fast-setting adhesives, which are sold as liquids in the presence of stabilizers. Rapid anionic polymerization on exposure to surface moisture is responsible for instant adhesion.
Cormac Duffy +2 more
doaj +1 more source
Automation of Controlled/Living Radical Polymerization
Controlled/living radical polymerization (CLRP) techniques are widely utilized to synthesize advanced and controlled synthetic polymers for chemical and biological applications.
Matthew Tamasi +4 more
doaj +1 more source

