Vinylic Addition Polynorbornene in Catalysis [PDF]
, 2019 Vinylic addition polynorbornenes (VA-PNB) result from the insertion polymerization of norbornene or specific norbornene derivatives catalyzed by transition metal com- plexes. The VA-PNB skeleton is completely aliphatic and keeps the bicyclic structure of
Albéniz Jiménez, Ana Carmen +1 more
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Surface structure of thin asymmetric PS-b-PMMA diblock copolymers investigated by atomic force microscopy [PDF]
, 2007 Asymmetric poly(styrene-b-methyl methacrylate) (PS-b-PMMA) diblock copolymers of molecular weight M-n = 29,700g mol(-1) (M-PS = 9300 g mol(-1) M-PMMA = 20,100 g mol(-1), PD = 1.15, chi(PS) = 0.323, chi(PMMA) = 0.677) and M-n = 63,900 g mol(-1) (M-PS = 50,
Hamley, Ian W. +3 more
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Intrazeolite assembly and pyrolysis of polyacrylonitrile [PDF]
, 1992 Radical polymerization of acrylonitrile within the pores of zeolites Y and mordenite produces intrazeolite polyacrylonitrile that can be pyrolysed to form conducting carbon ...
Bein, Thomas +2 more
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Unexpected polymerization mechanism of dilignol in the lignin growing [PDF]
Royal Society Open Science, 2019 Lignin is an essential component of higher plants, which is built by the enzymatic dehydrogenative polymerization of monolignols. First, monolignol is enzymatically oxidized to produce the phenoxy radical, which can form resonance hybrids.
Yasuyuki Matsushita +3 more
doaj +1 more source
Copper(0)-mediated radical polymerisation in a self-generating biphasic system [PDF]
, 2013 Herein, we demonstrate the synthesis of well-defined poly(n-alkyl acrylate)s via copper(0)-mediated radical polymerisation in a self-generating biphasic system. During the polymerisation of n-butyl acrylate in DMSO, the polymer phase separates to yield a
Amir Atme +53 more
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Effect of Oxygen and Initiator Solubility on Admicellar Polymerization of Styrene on Silica Surfaces
International Journal of Polymer Science, 2017 Although admicellar polymerization has been termed the surface analog of emulsion polymerization, previous reports utilizing free radical-initiated admicellar polymerization relied on high levels of the free radical initiator when compared to emulsion ...
Pohlee Cheah +3 more
doaj +1 more source
Synthesis and characterization of copolymers from hindered amines and vinyl monomers
Polímeros, 2014 New copolymers from hindered amines and vinyl monomers were synthesized by radical chain polymerization. To obtain polymeric HALS, acrylamide-(1ATP) and acrylate-(4ATP) monomers, derivatives from 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-4 ...
Marcelo Aparecido Chinelatto +2 more
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Molecular imprinting in hydrogels using reversible addition-fragmentation chain transfer polymerization and continuous flow micro-reactor [PDF]
, 2015 BACKGROUND Stimuli responsive imprinted hydrogel micro-particles were prepared using reversible addition-fragmentation chain transfer polymerization for targeting genotoxic impurity aminopyridine in aqueous environment using a continuous flow micro ...
Costa, Mário Rui +5 more
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Polymerization of organized monomers [PDF]
Hemijska Industrija, 2004 The current explanations of olefin and vinyl monomer polymerization propose that monomer molecules are successively added one by one to the growing polymer chain.
Stoiljković Dragoslav M. +6 more
doaj +1 more source
Sequential curing of amine-acrylate-methacrylate mixtures based on selective aza-Michael addition followed by radical photopolymerization [PDF]
, 2016 Dual curing systems find various uses in industry with the process flexibility they provide which allows tailoring properties at different curing stages in accordance with application requirements. A safe and efficient dual curing scheme is proposed here
Fernández Francos, Xavier +3 more
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