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Organometallic-Mediated Radical Polymerization [PDF]
Controlled radical polymerization has become increasingly important over the past decade and a half, allowing for the facile synthesis of specific macromolecular architectures with excellent control over the chemical and physical properties. This article
Allan, Laura E. N. +2 more
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2007
This volume from the successful Macromolecular Symposia series presents the contributions from the IUPAC-sponsored International Symposium on Radical Polymerization: Kinetics and Mechanism, held in Il Ciocco, Italy, in September, 2006. This was the fourth within the series of so-called SML conferences, which are the major scientific forum for ...
Buback, Michael, van Herk, A.M.
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This volume from the successful Macromolecular Symposia series presents the contributions from the IUPAC-sponsored International Symposium on Radical Polymerization: Kinetics and Mechanism, held in Il Ciocco, Italy, in September, 2006. This was the fourth within the series of so-called SML conferences, which are the major scientific forum for ...
Buback, Michael, van Herk, A.M.
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Concurrent atom transfer radical polymerization and nitroxide radical coupling relay polymerization
Chemical Communications, 2021Relay polymerization by conjugate radical trapping and re-initiation resulting in polymers with inserted alkoxyamine linkages.
Yu Wang +3 more
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Photoinduced Controlled Radical Polymerization
Macromolecular Rapid Communications, 2010AbstractWell‐controlled radical polymerization of methyl methacrylate can be achieved by in situ photochemical generation of copper (I) complex from air‐stable copper (II) species without using any reducing agent at room temperature. The living character of this polymerization was confirmed by both the linear tendency of molecular weight evolution with
Mehmet Atilla, Tasdelen +2 more
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Radical polymerization in biosensing
Analytical and Bioanalytical Chemistry, 2006This review briefly summarizes recently published work on radical polymerization in biosensor-related applications. Advancements in surface modification aimed at improving sensor biocompatibility and reducing nonspecific background noises are discussed.
Xinhui, Lou +3 more
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2015
Free-radical polymerization is a popular polymerization technique in both industry and research laboratories. This is attributed to the combined virtues of versatility, synthetic ease and compatibility with a wide variety of functional groups, coupled with its tolerance to water and protic media.
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Free-radical polymerization is a popular polymerization technique in both industry and research laboratories. This is attributed to the combined virtues of versatility, synthetic ease and compatibility with a wide variety of functional groups, coupled with its tolerance to water and protic media.
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Toward Living Radical Polymerization
Accounts of Chemical Research, 2008Radical polymerization is one of the most widely used processes for the commercial production of high-molecular-weight polymers. The main factors responsible for the preeminent position of radical polymerization are the ability to polymerize a wide array of monomers, tolerance of unprotected functionality in monomer and solvent, and compatibility with ...
Graeme, Moad +2 more
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Controlled Radical Polymerization of Styrene by Quinone Transfer Radical Polymerization (QTRP)
Macromolecules, 2004Radical polymerization of styrene falls under control when conducted at 100 °C in the presence of an ortho-quinone, e.g., phenanthrenequinone (PhQ), and a catalytic amount of cobalt(II) acetylacetonate. Criteria for a controlled chain polymerization are fulfilled at least until 50% of monomer conversion, i.e., molar mass increasing with monomer ...
Caille, Jean-Raphaël +2 more
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