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Stereocontrol in radical polymerization
The Chemical Record, 2001The stereospecific radical polymerization of vinyl esters, methacrylates, and alpha-substituted acrylates was studied. Fluoroalcohols, as a solvent, have remarkable effects on the stereoregularity of the radical polymerizations of vinyl acetate, vinyl pivalate, and vinyl benzoate, affording polymers rich in syndiotacticity, heterotacticity, and ...
S, Habaue, Y, Okamoto
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Macromolecules, 1998
Copper-catalyzed atom transfer radical polymerization (ATRP) is one of the most robust and precise techniques for controlling radical polymerization. The very good control of molecular weights, polydispersities, functionalities, chain composition, and topologies unusual for radical systems combined with the application of transition metals as catalysts
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Copper-catalyzed atom transfer radical polymerization (ATRP) is one of the most robust and precise techniques for controlling radical polymerization. The very good control of molecular weights, polydispersities, functionalities, chain composition, and topologies unusual for radical systems combined with the application of transition metals as catalysts
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Unconventional radical polymerizations
Pure and Applied Chemistry, 1984Abstract
C. I. Simionescu, B. C. Simionescu
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Radical Isomerization Polymerization
1999Generally, the monomers for radical polymerization are vinyl or vinylidene compounds. They afford the polymers which consist of a carbon-carbon single bond main chain through the normal addition polymerization mechanism. However, some monomer groups can rearrange during the propagation step, such as ring-opening reaction, ring-closing reaction, and ...
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Atom Transfer Radical Polymerization
Chemical Reviews, 2001K, Matyjaszewski, J, Xia
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