Results 31 to 40 of about 146,011 (308)

Absolut “copper catalyzation perfected”; robust living polymerization of NIPAM : Guinness is good for SET-LRP [PDF]

open access: yes
The controlled polymerization of N-isopropyl acrylamide (NIPAM) is reported in a range of international beers, wine, ciders and spirits utilizing Cu(0)-mediated living radical polymerization (SET-LRP).
Anastasaki, Athina   +25 more
core   +1 more source

Spark discharge-initiated radical polymerization

open access: yesNext Materials
A new spark discharge initiated radical polymerization (SDRP) was developed. Monomer radicals were generated by spark discharge emitted from a Tesla coil as a resonant transformer generating high frequency and high voltage, and the monomer itself acted ...
Hiromasa Goto   +3 more
doaj   +1 more source

Rapidly self-deoxygenating controlled radical polymerization in water via in situ disproportionation of Cu(i) [PDF]

open access: yes, 2020
Rapidly self-deoxygenating Cu-RDRP in aqueous media is investigated. The disproportionation of Cu(I)/Me6Tren in water towards Cu(II) and highly reactive Cu(0) leads to O2-free reaction environments within the first seconds of the reaction, even when the ...
Haddleton, David M.   +4 more
core   +1 more source

The cytoskeletal control of B cell receptor and integrin signaling in normal B cells and chronic lymphocytic leukemia

open access: yesFEBS Letters, EarlyView.
In lymphoid organs, antigen recognition and B cell receptor signaling rely on integrins and the cytoskeleton. Integrins act as mechanoreceptors, couple B cell receptor activation to cytoskeletal remodeling, and support immune synapse formation as well as antigen extraction.
Abhishek Pethe, Tanja Nicole Hartmann
wiley   +1 more source

A stepwise emergence of evolution in the RNA world

open access: yesFEBS Letters, EarlyView.
How did biological evolution emerge from chemical reactions? This perspective proposes a gradual scenario of self‐organization among RNA molecules, where catalytic feedback on random mixtures plays the central role. Short oligomers cross‐ligate, and self‐assembly enables heritable variations. An event of template‐externalization marks the transition to
Philippe Nghe
wiley   +1 more source

Anionic Polymerization Using Flow Microreactors

open access: yesMolecules, 2019
Flow microreactors are expected to make a revolutionary change in chemical synthesis involving various fields of polymer synthesis. In fact, extensive flow microreactor studies have opened up new possibilities in polymer chemistry including cationic ...
Yusuke Takahashi, Aiichiro Nagaki
doaj   +1 more source

B cell mechanobiology in health and disease: emerging techniques and insights into therapeutic responses

open access: yesFEBS Letters, EarlyView.
B cells sense external mechanical forces and convert them into biochemical signals through mechanotransduction. Understanding how malignant B cells respond to physical stimuli represents a groundbreaking area of research. This review examines the key mechano‐related molecules and pathways in B lymphocytes, highlights the most relevant techniques to ...
Marta Sampietro   +2 more
wiley   +1 more source

Novel Synthesis of Cellulose-Based Diblock Copolymer of Poly(hydroxyethyl methacrylate) by Mechanochemical Reaction

open access: yesThe Scientific World Journal, 2014
The mechanical fracture of polymer produces polymeric free radical chain-ends, by which liner block copolymers have been synthesized. A diblock copolymer of microcrystalline cellulose (MCC) and poly 2-hydroxyethyl methacrylate (pHEMA) was produced by the
Takeshi Ohura   +2 more
doaj   +1 more source

Radical chemistry in polymer science: an overview and recent advances

open access: yesBeilstein Journal of Organic Chemistry, 2023
Radical chemistry is one of the most important methods used in modern polymer science and industry. Over the past century, new knowledge on radical chemistry has both promoted and been generated from the emergence of polymer synthesis and modification ...
Zixiao Wang   +3 more
doaj   +1 more source

Disruption of SETD3‐mediated histidine‐73 methylation by the BWCFF‐associated β‐actin G74S mutation

open access: yesFEBS Letters, EarlyView.
The β‐actin G74S mutation causes altered interaction of actin with SETD3, reducing histidine‐73 methylation efficiency and forming two distinct actin variants. The variable ratio of these variants across cell types and developmental stages contributes to tissue‐specific phenotypical changes. This imbalance may impair actin dynamics and mechanosensitive
Anja Marquardt   +8 more
wiley   +1 more source

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