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Mathematical Modeling of Raft Polymerization
Computational Mathematics and Modeling, 2015A new mathematical model of Reversible Addition-Fragmentation chain Transfer (RAFT) polymerization is proposed, describing a series of experimental data on styrene bulk polymerization in the presence of various RAFT agents. The polymerization slowdown observed with increasing concentration of the RAFT agent is attributable to the accumulation of ...
N. L. Semendyaeva, S. I. Kuchanov
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Tailoring Polymeric Nanoparticles as Nanocarriers via RAFT Polymerization
World Chemical Engineering Journal, 2021Polymeric nanoparticles are really promising to be used as drug carriers, due to its ability to increase the aqueous solubility of drugs. Polymeric nanoparticles can regulate the drug activity by passive or active targeting to different tissues. RAFT polymerization has become the most approvable technique to synthesize polymeric nanocarriers for drug ...
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Morphology Transitions in RAFT Polymerization
Key Engineering Materials, 2012Diverse nanostructural materials including spheres, nanorods, vesicles, and large compound vesicles have been created via formation of amphiphilic ABA triblock copolymers, self-assembling and morphology transition in the reversible addition-fragmentation chain transfer (RAFT) dispersion polymerization.
Chuan Qun Huang, Cai Yuan Pan
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Kinetic Aspects of RAFT Polymerization
Macromolecular Symposia, 2007AbstractIn this short review, selected experimental approaches for probing the mechanism and kinetics of RAFT polymerization are highlighted. Methods for studying RAFT polymerization via varying reaction conditions, such as pressure, temperature, and solution properties, are reviewed.
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RAFT Miniemulsion Polymerization: Influence of the Structure of the RAFT Agent
Macromolecules, 2002Reversible addition−fragmentation chain transfer polymerization (RAFT) of styrene has been successfully performed in miniemulsion, mediated by a very efficient RAFT agent: 1-phenylethyl phenyldithioacetate (PEPDTA). To gain a better understanding of this system, we compared the performance of this RAFT agent with those of cumyl dithiobenzoate (CDB ...
Lansalot, Muriel +2 more
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Tailoring Polymer Dispersity by RAFT Polymerization: A Versatile Approach
CheM, 2020Richard Whitfield +2 more
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Orthogonal Cationic and Radical RAFT Polymerizations to Prepare Bottlebrush Polymers
Angewandte Chemie - International Edition, 2020Joji Tanaka +2 more
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