Beyond Traditional RAFT Polymerization: Emerging Strategies and Future Perspectives; A Third Update [PDF]
Advanced ScienceReversible addition–fragmentation chain transfer (RAFT) polymerization has undergone transformative growth since its inception in 1998, emerging as a powerful and versatile tool for precision polymer synthesis.
Vianna F. Jafari +10 more
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Photo-excited extracellular electron transfer of electroactive microorganism triggers RAFT polymerization [PDF]
Nature CommunicationsLiving cell-triggered reversible addition-fragmentation chain-transfer (RAFT) polymerization is of great value for construction of living materials with diverse applications.
Chao Li +13 more
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Smart and Efficient Synthesis of Cyclic Poly(N-isopropylacrylamide)s by Ring Expansion RAFT (RE-RAFT) Polymerization and Analysis of Their Unique Temperature-Responsive Properties [PDF]
MoleculesCyclic polymers have many interesting properties compared to their linear analogs, but there are very few examples of their synthesis. This is because most cyclic polymers have been synthesized by stepwise processes, including synthesizing homo- or ...
Jin Motoyanagi +2 more
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Photocontrolled RAFT polymerization: past, present, and future
Chemical Society Reviews, 2023 This review summarizes the development, progress, applications, and future challenges of photocontrolled reversible addition–fragmentation chain transfer (RAFT) polymerization, which has attracted considerable attention in the past several years.
Yungyeong Lee +2 more
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Progress and Perspectives Beyond Traditional RAFT Polymerization [PDF]
Advanced Science, 2020 The development of advanced materials based on well‐defined polymeric architectures is proving to be a highly prosperous research direction across both industry and academia.
Mitchell D. Nothling +8 more
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Development of Ring-Expansion RAFT Polymerization of tert-Butyl Acrylate with a Cyclic Trithiocarbonate Derivative toward the Facile Synthesis of Cyclic Polymers [PDF]
MoleculesPolymers with cyclic topology have no terminal structure and, therefore, exhibit various unique physical and functional properties compared to those of linear analogs.
Jin Motoyanagi +2 more
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Intermediate Radical Termination Theory in Elucidation of RAFT Kinetics and Comparison to Experimental Data [PDF]
علوم و تکنولوژی پلیمر, 2008 In current work a comprehensive mechanism based on intermediate radical termination theory is assumed for RAFT polymerization of styrene over cumyl dithiobenzoate as RAFT agent. Rate constants for addition (ka) and fragmentation reactions (kf) are set to
M. Baqeri-Jagharq +4 more
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The effect of RAFT polymerization on the physical properties of thiamphenicol-imprinted polymer
E3S Web of Conferences, 2018 The necessity to overcome limitation of conventional free radical polymerization, technology has shifted the way to find an effective method for polymer synthesis, called controlled radical polymerization (CRP). One of the most studied controlled radical
Yusof Noor Fadilah +2 more
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DNA–Polymer Conjugates by Photoinduced RAFT Polymerization [PDF]
Biomacromolecules, 2018 Conventional grafting-to approaches to DNA-polymer conjugates are often limited by low reaction yields due to the sterically hindered coupling of a presynthesized polymer to DNA. The grafting-from strategy, in contrast, allows one to directly graft polymers from an initiator that is covalently attached to DNA.
Thorsten Lueckerath +5 more
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Polímeros, 2014 Tamoxifen (TXF) is currently the only hormonal agent used for treatment of breast cancer. Although very effective, TXF presents low solubility in water, which affects its absorption and bioavailability.
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