Results 281 to 290 of about 107,791 (340)

Harnessing Carbenoid Reactivity From Imidazoles and Oxiranes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
The combination of azole compounds and oxiranes exhibits carbenoid reactivity at elevated temperatures, as demonstrated by the successful benzoin condensation of aromatic aldehydes. Using this catalytic system to polymerize bifunctional aldehyde/oxirane monomers yields thermosets with glass transition temperatures above 100°C.
Matthias R. Steiner   +4 more
wiley   +1 more source

Nanosecond anomaly detection with decision trees and real-time application to exotic Higgs decays. [PDF]

open access: yesNat Commun
Roche ST   +6 more
europepmc   +1 more source

Synthesis of Polysubstituted Tetrahydro‐1,4‐Thiazepines by Rhodium‐Catalyzed Ring Expansion of Dihydro‐1,3‐Thiazines with Diazoesters

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A rhodium(II)‐catalyzed ring expansion of stereodefined dihydro‐1,3‐thiazines with diazomalonates gives 1,4‐thiazepines via a sulfonium ylide rearrangement. The reaction shows a cis/trans reactivity divergence arising from different metal coordination, as revealed by experiments and density functional theory studies.
Laurine Tual   +3 more
wiley   +1 more source

CO2 Capture, Utilization, and Storage using Amino Acids

open access: yesAdvanced Sustainable Systems, EarlyView.
Amino acid and amino acid‐based ionic liquids show potential for sustainable CO2 capture, benefiting from reactive NH2 groups and low‐energy regeneration. Their use in solvents, functionalized sorbents, direct air capture, mineralization, and CO2 conversion highlights their versatilty and promise for advacing next‐generation CO2 sequestration ...
Md Sariful Sheikh   +3 more
wiley   +1 more source

Erbium-Implanted WS<sub>2</sub> Flakes with Room-Temperature Photon Emission at Telecom Wavelengths. [PDF]

open access: yesNano Lett
García-Arellano G   +6 more
europepmc   +1 more source

Excessive DNA Double‐Strand Breaks–Associated 3D Genome Reorganization Contributes to Neural Tube Defects with Folate Deficiency

open access: yesAdvanced Science, EarlyView.
Neural tube defects (NTDs) are among the most common congenital malformations. However, the underlying etiology and mechanism remain elusive. Here, the role of DNA double‐strand breaks (DSBs) in 3D genome organization within the NTDs with folate deficiency is reported.
Ting Zhang   +12 more
wiley   +1 more source

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