Results 151 to 160 of about 1,197 (262)

Coastal land uplift and intensified land-use influence seagrass carbon and nitrogen sink capacity over millennial timescales. [PDF]

open access: yesSci Rep
Dahl M   +19 more
europepmc   +1 more source

Alkali‐Metal Base Catalyzed Electrocyclization of Isoprene Derivatives

open access: yesChemistry – A European Journal, EarlyView.
Simple and abundant alkali‐metal base catalysis in combination with Lewis basic polyamines enables the electrocyclization of isoprene‐derived trienes to cycloheptadienes under neat conditions. Mechanistic insight supported by DFT guides a scalable route to seven‐membered carbocycles which, after reduction, give saturated cycloalkanes relevant as ...
Mikaël Le Roch   +3 more
wiley   +1 more source

Multidisciplinary evidence for synchroneity between Ontong Java Nui volcanism and early Aptian oceanic anoxic event 1a. [PDF]

open access: yesSci Adv
Matsumoto H   +8 more
europepmc   +1 more source

Self‐Complementary Dimers Based on Zwitterionic Halogen Bond Donors

open access: yesChemistry – A European Journal, EarlyView.
In this study we present the first isolated zwitterionic homodimers based on halogen bonding (XB). After optimization of the structures by changing the Lewis base (LB) and the backbone, their dimerization was observed in gas phase, as well as, in solid state.
Dana Kutzinski   +5 more
wiley   +1 more source

Combining isotope ratios for provenancing Viking Age iron artefacts in the British Isles: a pilot study. [PDF]

open access: yesRSC Adv, 2023
Harding SE   +9 more
europepmc   +1 more source

Dinuclear Copper(I) Complexes Featuring Metal–Metal Interactions and a μ2‐Bridging Phosphane With Additional Olefinic Binding Sites

open access: yesChemistry – A European Journal, EarlyView.
A Cu2P triangle captured in a tetrapodal phosphane tris(olefin) ligand, where all binding forces are weak apart from the Cu─P interaction. ABSTRACT The molecule Ptrop3 contains in each trop unit (trop = dibenzo[a,d]cyclohepten‐5‐yl) a rigid central seven‐membered ring with an olefinic binding site making Ptrop3 potentially a tetradentate ligand ...
Zhongshu Li   +6 more
wiley   +1 more source

Breaking the Mold: Electrophilic Hydrophosphanation Emerges

open access: yesChemistry – A European Journal, EarlyView.
Electrophilic hydride attack on the olefin, instead of the classical nucleophilic addition by a phosphanido ligand, is unveiled in rhodium‐catalyzed olefin hydrophosphanation. This hydride‐driven pathway operates for both activated and inactivated olefins, with transition states characterized by elongated Rh─H bonds and nascent C─H bond formation ...
Víctor Varela‐Izquierdo   +4 more
wiley   +1 more source

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