Coastal land uplift and intensified land-use influence seagrass carbon and nitrogen sink capacity over millennial timescales. [PDF]
Dahl M +19 more
europepmc +1 more source
Alkali‐Metal Base Catalyzed Electrocyclization of Isoprene Derivatives
Simple and abundant alkali‐metal base catalysis in combination with Lewis basic polyamines enables the electrocyclization of isoprene‐derived trienes to cycloheptadienes under neat conditions. Mechanistic insight supported by DFT guides a scalable route to seven‐membered carbocycles which, after reduction, give saturated cycloalkanes relevant as ...
Mikaël Le Roch +3 more
wiley +1 more source
Multidisciplinary evidence for synchroneity between Ontong Java Nui volcanism and early Aptian oceanic anoxic event 1a. [PDF]
Matsumoto H +8 more
europepmc +1 more source
Self‐Complementary Dimers Based on Zwitterionic Halogen Bond Donors
In this study we present the first isolated zwitterionic homodimers based on halogen bonding (XB). After optimization of the structures by changing the Lewis base (LB) and the backbone, their dimerization was observed in gas phase, as well as, in solid state.
Dana Kutzinski +5 more
wiley +1 more source
Reply to: Reassessing gas generation from oil thermal cracking associated with the Emeishan Large Igneous Province. [PDF]
Chen C +6 more
europepmc +1 more source
Combining isotope ratios for provenancing Viking Age iron artefacts in the British Isles: a pilot study. [PDF]
Harding SE +9 more
europepmc +1 more source
A Cu2P triangle captured in a tetrapodal phosphane tris(olefin) ligand, where all binding forces are weak apart from the Cu─P interaction. ABSTRACT The molecule Ptrop3 contains in each trop unit (trop = dibenzo[a,d]cyclohepten‐5‐yl) a rigid central seven‐membered ring with an olefinic binding site making Ptrop3 potentially a tetradentate ligand ...
Zhongshu Li +6 more
wiley +1 more source
A revised radiocarbon chronology for the mammoth bone structures and associated features at Mezhyrich, Ukraine. [PDF]
Chu W, Shydlovskyi P, Maier A.
europepmc +1 more source
Breaking the Mold: Electrophilic Hydrophosphanation Emerges
Electrophilic hydride attack on the olefin, instead of the classical nucleophilic addition by a phosphanido ligand, is unveiled in rhodium‐catalyzed olefin hydrophosphanation. This hydride‐driven pathway operates for both activated and inactivated olefins, with transition states characterized by elongated Rh─H bonds and nascent C─H bond formation ...
Víctor Varela‐Izquierdo +4 more
wiley +1 more source

