Results 51 to 60 of about 1,197 (262)

Biomimetic Polymerization of Tellurocysteine: Breaking the Natural Amino Acid Radioprotection Limitation

open access: yesAdvanced Science, EarlyView.
Inspired by natural amino acid polymer‐melanin systems, this study strategically incorporated tellurocysteine to develop advanced radiation‐shielding materials. This approach transformed the primary interaction mechanism between melanin‐based materials and incident photons from Compton scattering to the photoelectric effect. Tellurocysteine‐polymerized
Wei Chen   +6 more
wiley   +1 more source

Radiation‐Resistant Kr‐Selective MOF With Record Kr/Xe Selectivity at Elevated Pressure

open access: yesAdvanced Science, EarlyView.
ABSTRACT The separation of Kr/Xe from spent nuclear fuel off‐gas is critical, yet most current adsorbents exhibit Xe‐Kr co‐adsorption under elevated pressures, posing challenges for industrial pressure swing adsorption processes. Herein, we present and evaluate a metal‐organic framework, CALF‐20M‐w, engineered for molecular sieving separation of Kr/Xe ...
Qihang Tian   +6 more
wiley   +1 more source

Revisiting Target‐Aware de novo Molecular Generation with TarPass: Between Rational Design and Texas Sharpshooter

open access: yesAdvanced Science, EarlyView.
TarPass provides a rigorous benchmark for target‐aware de novo molecular generation by jointly evaluating protein‐ligand interactions, molecular plausibility, and drug‐likeness on 18 well‐studied targets. Results show that current models often fail to consistently surpass random baseline in target‐specific enrichment, while post hoc multi‐tier virtual ...
Rui Qin   +11 more
wiley   +1 more source

Re-Os isotope dating of pyrite from the footwall mineralization zone of the Xinqiao deposit, Tongling, Anhui Province: Geochronological evidence for submarine exhalative sedimentation [PDF]

open access: yesChinese Science Bulletin, 2011
The Xinqiao deposit is located in the Tongling area, Anhui Province. This deposit is dominantly composed of stratiform sulfide orebodies, which are restricted to the transitional zone from clastic rocks to carbonates at the base of the Late Carboniferous Huanglong Formation.
Guo, WeiMin   +4 more
openaire   +1 more source

Role of Terrestrial Organic Matter in Re and Os Uptake: Insights for Re-Os Dating of Organic-Bearing Sedimentary Rocks and Weathering of Organic Carbon [PDF]

open access: yes
The rhenium-osmium (Re-Os) isotope system is a powerful tool for dating organic-rich sedimentary rocks, yet the mechanisms of Re and Os uptake and their fractionation in different types of organic matter remain poorly understood. Here, we investigate the
Zhou, Fuming   +4 more
core   +1 more source

Selection and Treatment of Data for Radiocarbon Calibration: An Update to the International Calibration (IntCal) Criteria [PDF]

open access: yes, 2013
High-quality data from appropriate archives are needed for the continuing improvement of radiocarbon calibration curves. We discuss here the basic assumptions behind 14C dating that necessitate calibration and the relative strengths and weaknesses of ...
Beck, J. Warren,   +112 more
core   +1 more source

Cobalt Single‐Atom Catalysts for Ultrafast Sulfamethoxazole Degradation: Unveiling the Chloride‐Ion‐Enhanced Formation of Co(IV)=O

open access: yesAdvanced Science, EarlyView.
An atomically dispersed Co–N4 single‐atom catalyst rapidly activates peroxymonosulfate to remove the antibiotic sulfamethoxazole from water. Common ions have little impact, but chloride dramatically speeds degradation by promoting a high‐valent Co(IV) = O oxidant via in situ HOCl–catalyst electron transfer.
Anting Ding   +6 more
wiley   +1 more source

A Symmetric Cogeneration Fuel Cell for Coupled Production of Hydrogen, Ammonia and Formate

open access: yesAdvanced Science, EarlyView.
A symmetric cogeneration fuel cell integrating value‐added chemical synthesis with electricity generation by coupling formaldehyde oxidation with the nitrate reduction was developed. This work highlights the broader potential of symmetric cogeneration fuel cells as a general platform for rational reaction pairing, offering a practical pathway to lower ...
Yingjie Song   +8 more
wiley   +1 more source

First in situ Re-Os dating of molybdenite by LA-ICP-MS/MS

open access: yes, 2019
Conventional dating of molybdenite (Re-187-Os-187) provides one of few options for direct dating of sulfide mineralization. Unfortunately, in situ dating of molybdenite is considered unreliable due to intra-granular decoupling of Re-187-Os-187.
Fridolfsson, Irma,   +3 more
core   +1 more source

Tailored D‐π Conjugation Boosts Piezocatalytic CO2 Reduction in a Platinum(II)‐Acetylide Framework

open access: yesAdvanced Science, EarlyView.
The highly conjugated metalII‐acetylide framework demonstrates efficient ultrasound‐driven conversion of CO2 to CO. The piezoelectric field generated by ultrasound facilitates electron transfer from the tetraphenylene π‐column to the MII‐bis(acetylide) moiety, enabling CO2 activation. Compared to PdII‐ and NiII‐based analogues, the stronger d–π orbital
Mude Zhu   +6 more
wiley   +1 more source

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