Results 141 to 150 of about 1,126 (270)

The Asymmetric Self‐Replicative Alkylation of N‐Arylaldimines Using Organolithium Reagents

open access: yesChemistry – A European Journal, EarlyView.
Here, we report a new asymmetric autoinductive reaction; the addition of nBuLi to N‐arylaldimines to form chiral lithium amides. The reaction proceeds with full conversion and complete transfer of chirality, representing the first example of an asymmetric autoinductive reaction with organolithium reagents.
Anka Hagelschuer   +2 more
wiley   +1 more source

Rapid coupling between solid earth and ice volume during the Quaternary. [PDF]

open access: yesSci Rep, 2021
Kuwahara Y   +9 more
europepmc   +1 more source

Breaking the Mold: Electrophilic Hydrophosphanation Emerges

open access: yesChemistry – A European Journal, EarlyView.
Electrophilic hydride attack on the olefin, instead of the classical nucleophilic addition by a phosphanido ligand, is unveiled in rhodium‐catalyzed olefin hydrophosphanation. This hydride‐driven pathway operates for both activated and inactivated olefins, with transition states characterized by elongated Rh─H bonds and nascent C─H bond formation ...
Víctor Varela‐Izquierdo   +4 more
wiley   +1 more source

Visible‐Light Driven Acetylene Semi‐Hydrogenation to Ethylene With a Copper Photosensitizer and a Cobaloxime Catalyst

open access: yesChemistry – A European Journal, EarlyView.
A fully noble‐metal‐free photocatalytic system that couples cobaloxime catalysis with Cu photosensitizer for HAT‐driven acetylene‐to‐ethylene conversion is reported. ABSTRACT The purification of ethylene streams from acetylene impurities remains a key industrial challenge, for which light‐powered strategies are emerging as sustainable alternatives to ...
Anna Fortunato   +5 more
wiley   +1 more source

Relationships among tissues, biofluids, and otolith selenium concentrations in wild female burbot (Lota lota)

open access: yesIntegrated Environmental Assessment and Management, EarlyView., 2023
Abstract In the Lake Koocanusa‐Kootenai River system (Montana, USA and British Columbia, Canada), selenium (Se) contamination has become an international concern and is suspected to contribute to the observed burbot (Lota lota) population collapse. Due to our limited ability to sample burbot in Lake Koocanusa for monitoring studies, we used a reference
Stephanie D. Graves   +6 more
wiley   +1 more source

Multidisciplinary evidence for synchroneity between Ontong Java Nui volcanism and early Aptian oceanic anoxic event 1a. [PDF]

open access: yesSci Adv
Matsumoto H   +8 more
europepmc   +1 more source

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