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Calculations of parabolic reaction rate constants
Oxidation of Metals, 1987The oxidation kinetics of only a very limited number of pure metals or binary alloys can be described by the simplest parabolic law, Δm2=kpt, Thus for a transient period of faster kinetics, the steady state parabolic law is given by (Δm−Δmi)2 = kp(t−ti) when the initial weight gain Δmi does not contribute to steady state rate control. In such a case, a
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Determination the rate constants of some biexponential reactions
Journal of Biochemical and Biophysical Methods, 2000Reactions that are described by biexponential functions are typical for many biological processes. The kinetics of these reactions is described by transcendental irrational equations interconnecting the reagent concentrations, time and rate constants.
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Improved Calculation of Quasiequilibrium Reaction Rate Constants
The Journal of Chemical Physics, 1963The method of steepest descents has been applied to the calculation of the total number of quantum states of a system of harmonic oscillators. The corresponding rate expressions of unimolecular reactions have also been derived.
S. H. Lin, Henry Eyring
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Rate Constant of the Reaction between CH3O2 Radicals and OH Radicals Revisited.
Journal of Physical Chemistry A, 2016E. Assaf +4 more
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Journal of Physical Chemistry A, 2014
V. L. Orkin, L. E. Martynova, M. Kurylo
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V. L. Orkin, L. E. Martynova, M. Kurylo
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An example of a constant rate reaction
Journal of Chemical Education, 1987A simple experiment whose rate of reaction (a burning candle) proceeds at constant conditions.
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Hydroxyl radical reaction rate constant model
2011Tropospheric photochemical air pollution has impacts on scales ranging from local to global. Reactions with hydroxyl radical (OH.) is the most important pathway of day time removal of organic pollutants in atmosphere. Theoretical approaches as QSAR/QSPRs are often used to predict the high risk of organic chemicals to reduce the time consuming ...
Roy P. P. +3 more
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