Results 61 to 70 of about 1,822,559 (326)

Kinetics and Mechanism of Mn(II) Catalyzed Periodate Oxidation of p-anisidine: Effect of pH

Bulletin of Chemical Reaction Engineering & Catalysis, 2014
The stoichiometry for the initial part of the reaction, Mn(II) catalysed periodate oxidation of p-anisidine (PMA), has been found to be 1 mol of PMA consuming 2 mol of periodate ion.
Rajneesh Dutt Kaushik, Jaspal Singh, M. Manila, Manmeet Kaur, Prabha Singh   +4 more
doaj   +1 more source

Effect of different choices of the Boltzmannized flux operator on thermal exchange and recombination reactions

, 2003
The rate constants for recombination and exchange reactions are calculated using the flux correlation approach with a general form of the Boltzmannized flux operator, which can simultaneously describe the Kubo and traditional half-split forms.
Chandler, Feynman, Germann, Hänggi, Koichi Saito, Kubo, Kubo, Leforestier, Mandelshtam, Miller, Miller, Miller, Miller, Miller, Mori, Qi, Saito, Schulman, Smedarchina, Sun, Thompson, Voth, Wolynes, Yamamoto, Yamamoto, Zang   +25 more
core   +1 more source

Time-resolved gas-phase kinetic and quantum chemical studies of the reaction of silylene with oxygen [PDF]

, 2005
Time-resolved kinetic studies of the reaction of silylene, SiH2, generated by laser flash photolysis of phenylsilane, have been carried out to obtain rate constants for its bimolecular reaction with O-2. The reaction was studied in the gas phase over the
Adamovic, I., Almond, M.J., Becerra, R., Bowes, S.J., Cannady, J.P., Gordon, M.S., Ogden, J.S., Walsh, R.   +7 more
core   +1 more source

Peripheral blood proteome biomarkers distinguish immunosuppressive features of cancer progression

Molecular Oncology, EarlyView.
Immune status significantly influences cancer progression. This study used plasma proteomics to analyze benign 67NR and malignant 4T1 breast tumor models at early and late tumor stages. Immune‐related proteins–osteopontin (Spp1), lactotransferrin (Ltf), calreticulin (Calr) and peroxiredoxin 2 (Prdx2)–were associated with systemic myeloid‐derived ...
Yeon Ji Park, Jae Won Oh, Hyewon Chung, Jung Won Kwon, Yi Rang Na, Kwang Pyo Kim, Seung Hyeok Seok   +6 more
wiley   +1 more source

The Oxidation of 2-(2-Methoxyethoxy)ethanol and 2-(2-Ethoxyethoxy)ethanol by Ditelluratocuprate(III): A Kinetic and Mechanistic Study

Journal of Chemistry, 2013
The oxidation of 2-(2-methoxyethoxy)ethanol (MEE) and 2-(2-ethoxyethoxy)ethanol (EEE) by ditelluratocuprate(III) (DTC) had been studied spectrophotometrically in alkaline medium.
Jin-huan Shan, Yi Li, Shu-ying Huo, Cai-hong Yin   +3 more
doaj   +1 more source

The intrinsic rate constants in diffusion-influenced reactions

Faraday Discussions, 2016
Intrinsic rate constants play a dominant role in the theory of diffusion-influenced reactions, but usually as abstract quantities that are implicitly assumed to be known. However, recently it has become clear that modeling complex processes requires explicit knowledge of these intrinsic rates.
Peter G. Bolhuis, Adithya Vijaykumar, Adithya Vijaykumar, Pieter Rein ten Wolde   +3 more
openaire   +4 more sources

Targeting the MDM2‐MDM4 interaction interface reveals an otherwise therapeutically active wild‐type p53 in colorectal cancer

Molecular Oncology, EarlyView.
This study investigates an alternative approach to reactivating the oncosuppressor p53 in cancer. A short peptide targeting the association of the two p53 inhibitors, MDM2 and MDM4, induces an otherwise therapeutically active p53 with unique features that promote cell death and potentially reduce toxicity towards proliferating nontumor cells.
Sonia Valentini, Giada Mele, Marika Attili, Maria Rita Assenza, Fulvio Saccoccia, Francesca Sardina, Cinzia Rinaldo, Roberto Massari, Nicola Tirelli, Alfredo Pontecorvi, Fabiola Moretti   +10 more
wiley   +1 more source

Rate constant of the reaction between CH3O2 and OH radicals [PDF]

Chemical Physics Letters, 2014
Abstract The rate constant of the reaction (R1) OH + CH 3 O 2 → products has been measured at 294 K by simultaneous coupling of Laser Induced Fluorescence (LIF) and cw-Cavity Ring Down Spectroscopy (cw-CDRS) to laser photolysis. OH radicals were generated by 248 nm photolysis of either H 2 O 2 or O 3 in the presence of H
Eszter Pongráczné Faragó, Eszter Pongráczné Faragó, Christa Fittschen, Coralie Schoemaecker, Adriana Gabriela Bossolasco, Adriana Gabriela Bossolasco   +5 more
openaire   +4 more sources

Aberrant expression of nuclear prothymosin α contributes to epithelial‐mesenchymal transition in lung cancer

Molecular Oncology, EarlyView.
Nuclear prothymosin α inhibits epithelial‐mesenchymal transition (EMT) in lung cancer by increasing Smad7 acetylation and competing with Smad2 for binding to SNAI1, TWIST1, and ZEB1 promoters. In early‐stage cancer, ProT suppresses TGF‐β‐induced EMT, while its loss in the nucleus in late‐stage cancer leads to enhanced EMT and poor prognosis.
Liyun Chen, Chung‐Teng Wang, Jia‐Ming Chang, Ai‐Li Shiau, Gia‐Shing Shieh, Yau‐Lin Tseng, Yi‐Ting Yen, Tang‐Hsiu Huang, Li‐Hsin Cheng, Yu‐Chih Wu, Chao‐Liang Wu, Bing‐Hua Su, Pensee Wu   +12 more
wiley   +1 more source

Chemical kinetics computer program for static and flow reactions [PDF]

, 1972
General chemical kinetics computer program for complex gas mixtures has been developed. Program can be used for any homogeneous reaction in either one dimensional flow or static system. It is flexible, accurate, and easy to use.
Bittker, D. A., Scullin, V. J.
core   +1 more source