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Disorder‐Driven Ionic Mobility Edge and Localization‐Driven Dendrite Formation in Solid Electrolytes
Migration‐barrier disorder localizes ionic transport into a sparse percolation backbone. Current and electric‐field focusing at filament tips promote fractal dendrite growth and suppress the critical current density according to jcrit = j0 exp(−σEeff/kBT).
Dongwook Lee, Jiwon Seo
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As demand for Li‐ion batteries grows, Mn‐rich disordered rocksalt (DRX) oxides offer a sustainable, low‐cost alternative to scarce Ni and Co. During cycling, Mn‐rich DRX materials transform into a partial spinel‐like phase (𝛿) that improves rate capability and capacity.
Han‐Ming Hau +12 more
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Expansion during the reaction sintering of PZT
Ceramurgia International, 1980Abstract Expansion during the reaction sintering of PZT from PT and PZ constituents was studied at different molar ratios, for different particle sizes, and different temperatures: compositional and particle size effects were observed. The expansion is related to the size of the PT particles present and exhibits a maximum at 50 mole% PT for equal ...
Yoshikazu Nakamura +2 more
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Reaction sintering: correlation between densification and reaction
Journal of Materials Science, 1979By studying simultaneous densification kinetics and reaction kinetics during the sintering and hot pressing of alumina-zircon mixtures, it has been possible to distinguish between the particle rearrangement and particle reshaping (diffusive) stages of the densification process. Particle rearrangement is found to be more significant during hot pressing (
E. Di Rupo, M. R. Anseau, R. J. Brook
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2008
Recent results suggest that Li + can substitute for Al 3+ in the gamma-AlON structure. LiAl 5 O 8 is isostructural with gamma-AlON above 1290°C after it goes through an ordered-disordered phase transformation and has a similar lattice parameter. A previous study showed the benefits of reaction sintering LiAlON starting with LiAl 5 O 8 as compared ...
Raymond A. Cutler, R. Marc Flinders
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Recent results suggest that Li + can substitute for Al 3+ in the gamma-AlON structure. LiAl 5 O 8 is isostructural with gamma-AlON above 1290°C after it goes through an ordered-disordered phase transformation and has a similar lattice parameter. A previous study showed the benefits of reaction sintering LiAlON starting with LiAl 5 O 8 as compared ...
Raymond A. Cutler, R. Marc Flinders
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Reaction Sintering of Uranium Monocarbide
Transactions of the Indian Ceramic Society, 1975High density (95% theoretical) single-phase uranium monocarbide has been fabricated by warm pressing a mixture of suitably sized dicarbide and uranium metal powders at 800°C at 675 kg/cm2 for 5 minutes and by subsequent sintering at 600°-1000°C. The high density and the single phase structure could be retained upto 1800°C, though some grain growth ...
B. D. Zope, V. K. Moorthy
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Hydrothermal reaction sintering of monoclinic zirconia
1989A dense monoclinic zirconia ceramic having a maximum density of 5.85 g/cm3 and grains of 1–5 µm has been prepared from Zr metal powder and water in a Pt capsule by hydrothermal reaction sintering at 1000°C for 3 h under 98 MPa. The effects of temperatures, pressures, and initial compositions on the densification and sintering were studied. The reaction
Masahiro Yoshimura, Shigeyuki Sômiya
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Sintering Reactions of Zinc Oxide
Journal of Applied Physics, 1959The sintering of zinc oxide spheres has been studied in the temperature range 700 to 900°C in air, oxygen, helium, and hydrogen. Fresh zinc oxide sinters rapidly in air and oxygen, but it does not sinter appreciably in helium in the same temperature range.
V. J. Lee, G. Parravano
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Reactions for Hydrothermal Reaction Sintering
1990Metal powders or chips were reacted with high temperature and high pressure solution to form oxides under certain hydrothermal conditions.
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Synthesis of hercynite by reaction sintering
Journal of the European Ceramic Society, 2011Abstract Hercynite was synthesized by a reaction sintering method using industrial alumina, mill scale, and carbon black as starting materials in the presence of nitrogen and solid carbon at high temperatures. Phase and microstructure changes during the synthesis were investigated. The specimen sintered at 1450 °C consisted of hercynite (FeO·Al 2 O 3
Junhong Chen +4 more
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