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Hydrogenation Study of NaF/NaH/MgB2 Reactive Hydride Composites

The Journal of Physical Chemistry C, 2017
The hydrogenation of NaF/9NaH + 5MgB2 and NaF/2NaH + 1.5MgB2 reactive hydride composites (RHC) was studied by volumetric titration (kinetics and PCI curves), in situ synchrotron radiation powder X-ray diffraction (SR-PXD), high-pressure differential scanning calorimetry (HP-DSC), Fourier transform infrared spectroscopy (FT-IR), and scanning electron ...
J. L. Carrillo-Bucio   +6 more
semanticscholar   +2 more sources

Synchrotron Diffraction Studies of Hydrogen Absorption/Desorption on CaH2 + MgB2 Reactive Hydride Composite Mixed With Fluorinated Compounds

The Journal of Physical Chemistry C, 2015
The reactive hydride composites 9CaH2 + CaF2 + 10MgB2, 10Ca(BH4)2 + 9MgH2 + MgF2, and 9Ca(BH4)2 + Ca(BF4)2 + 10MgH2 were prepared by ball milling.
K. Suárez-Alcántara   +7 more
semanticscholar   +2 more sources

Milling time effect of Reactive Hydride Composites of NaFNaHMgB2 investigated by in situ powder diffraction

International Journal of Hydrogen Energy, 2016
Abstract Light metal complex borohydrides have high hydrogen storage capacities but suffer from drawbacks of slow hydrogen sorption kinetics, poor reversibility and high thermodynamic stability. The NaF + 9NaH + 5MgB2 composite has a theoretical hydrogen capacity of 7.7 wt% H assuming the formation of 10NaBH3.9F0.1 + 5MgH2.
M. Heere   +4 more
semanticscholar   +2 more sources

Silicone copolymers bearing reactive vinyl and hydride functionalities: Synthesis, characterisation and particulate composite thereof for specialty applications

Materials Chemistry and Physics, 2018
Abstract High molecular weight vinyl terminated poly (dimethyl-co-diphenyl)siloxane polymer (V-PDMPS) was synthesised by a multistage process including hydrolysis of precursor chlorosilanes and their anionic polymerization followed by chain termination.
K. Indulekha   +5 more
semanticscholar   +2 more sources

A review on 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: Performance optimization and perspectives

Journal of Energy Storage
Kai Jia   +6 more
semanticscholar   +2 more sources

Probing an intermediate state by X-ray absorption near-edge structure in nickel-doped 2LiBH4–MgH2 reactive hydride composite at moderate temperature

, 2020
Transition metal nickel (Ni) efficiently provoke an enhanced hydrogen desorption kinetics of 2LiBH4-MgH2 reactive hydride composite (RHC) system by in-situ formed MgNi3B2.
X. Huang   +9 more
semanticscholar   +1 more source

In-situ formation of ultrafine MgNi3B2 and TiB2 nanoparticles: Heterogeneous nucleating and grain coarsening retardant agents for magnesium borate in Li–Mg–B–H reactive hydride composite

International journal of hydrogen energy, 2019
Li–Mg–B–H reactive hydride composite (RHC) has attracted extensive attention over the past decades for its extremely high hydrogen storage capacity (11.5 wt%).
Xu Huang   +6 more
semanticscholar   +1 more source

Unexpected kinetic effect of MgB2 in reactive hydride composites containing complex borohydrides

Journal of Alloys and Compounds, 2007
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Gagik Barkhordarian   +3 more
openaire   +1 more source

In-Situ Deposition of Alkali and Alkaline Earth Hydride Thin Films To Investigate the Formation of Reactive Hydride Composites

The Journal of Physical Chemistry C, 2010
We investigate the critical steps in the formation of Ca ...
Gonzalez-Silveira, M.   +9 more
openaire   +3 more sources

A new mutually destabilized reactive hydride system: LiBH4–Mg2NiH4

Journal of Energy Chemistry, 2019
In this work, the hydrogen sorption properties of the LiBH4–Mg2NiH4 composite system with the molar ratio 2:2.5 were thoroughly investigated as a function of the applied temperature and hydrogen pressure.
N. Bergemann   +8 more
semanticscholar   +1 more source

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