Results 201 to 210 of about 193,851 (310)

Electronic‐State Programming of Ultrasmall CeO2 Switches H2O2 Activation From Radical to Bio‐Inspired Nonradical 1O2 Generation for Combating Antibiotic Resistance

open access: yesAdvanced Science, EarlyView.
A scalable synthesis of carbon‐supported ultrasmall CeO2 nanoparticles with precisely tunable Ce electron density is reported. Electron‐lean Ce sites activate H2O2 exclusively via a nonradical pathway, enabling efficient HOBr and 1O2 production analogous to bromoperoxidase for contaminant and antibiotic resistance removal.
Bo Yuan   +10 more
wiley   +1 more source

Molecular Electrocatalysis Coupled With a Palladium Membrane Reactor Affords Selective Nitrogen Reduction

open access: yesAdvanced Science, EarlyView.
A palladium membrane reactor delivers active hydrogen to homogeneous nickel terpyridine catalysts, which then selectively hydrogenate dinitrogen to ammonia. ABSTRACT Ammonia production is a cornerstone of modern industry and society, yet the conventional Haber–Bosch process accounts for nearly 2% of the global CO2 emissions. A promising and potentially
Morgan McKee   +11 more
wiley   +1 more source

Electron‐Rich Nickel Enabled by Charge Transfer in Multimetal Nanostructures for Efficient Ammonia‐to‐Hydrogen Conversion

open access: yesAdvanced Science, EarlyView.
A charge‐transfer‐engineered Ni catalyst derived from an atomically mixed layered precursor enables efficient ammonia‐to‐hydrogen conversion. Cr‐to‐Ni electron transfer creates electron‐rich Ni active sites that favor NH3 adsorption, modify the dehydrogenation energetics, and weaken N2 binding to facilitate product desorption. This electronically tuned
Donghyeok Kim   +9 more
wiley   +1 more source

Hydrogen Production from Ammonia Electrochemical Cracking

open access: yesAdvanced Science, EarlyView.
NH3 electrochemical cracking (e‐cracking) is a complementary technique to centralized thermal cracking for releasing H2 from NH3. In this article, we review recent advances in catalyst development for these cracking techniques and conduct a techno‐economic analysis (TEA) to evaluate the economic feasibility of e‐cracking.
Yike Ye   +4 more
wiley   +1 more source

Deciphering Microbial Communities in MEC-AD reactors

open access: yes
Microbial electrolysis cell–assisted anaerobic digestion (MEC-AD) is an emerging technology with the potential to enhance biogas yields and selectively increase methane content through bioelectrochemical stimulation. However, practical deployment remains
Ahmaditabatabaei, S., Kyazze, G.
core  

Product‐Reshaped Gas‐Phase Hydrodynamics Govern CO2 Electrolysis in Gas Diffusion Electrodes

open access: yesAdvanced Science, EarlyView.
In gas‐fed CO2${\rm CO}_2$ electrolysers, the gas phase is part of the electrochemical response. As gaseous products form, they change gas composition and flow, which in turn affects CO2${\rm CO}_2$ delivery and CO intermediate availability. This feedback changes the reaction environment needed for multicarbon formation, becoming unavoidable as ...
Abdullah A. Alyahya   +6 more
wiley   +1 more source

Black Silicon for Solar Fuels

open access: yesAdvanced Science, EarlyView.
Black silicon couples broadband light harvesting with high‐surface‐area catalytic interfaces, offering a versatile photoelectrode platform for solar‐fuel production. Reaction‐specific analysis highlights trade‐offs involving recombination, chemical instability, catalyst‐induced optical shielding, competing reactions, and mass transport.
Neul Ha, Kaiying Wang, Wooseok Yang
wiley   +1 more source

Synergistic Charge Scavenging in Pt/C‐Polyoxometalate Systems for Scalable Biomass Power Generation via Super‐Reduced Electrolytes

open access: yesAdvanced Science, EarlyView.
Synergistic charge scavenging between Pt/C and liquid polyoxometalate mediators effectively dismantles the inherent biological recalcitrance of raw biowaste. This dynamic interfacial electron transfer unlocks a multi‐electron super‐reduced state (>4 electrons). By overcoming traditional electron‐harvesting ceilings, this approach enables scalable, high‐
Hojin Lee   +6 more
wiley   +1 more source

Deciphering Electrochemical Generation, Transport, and Reactivity of Hydrogen Species in the Electrochemical Palladium Membrane Reactor

open access: yesAdvanced Science, EarlyView.
This study elucidates hydrogen transport and reaction mechanisms in ePMR using 1‐hexyne hydrogenation as a model reaction. Hydrogen transport operates via dual pathways involving hydrogen atom permeation and H2‐mediated re‐dissociation on secondary metal layers.
Samuel J. Shin   +6 more
wiley   +1 more source

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