Quest for 2,3-Secopyramidane: Computations Hint at Elusive Structure during Skattebo̷l Rearrangement of Vinylcyclopropylidene∇. [PDF]
Rosenberg MG, Brinker UH.
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Small Copy Number Neutral Intrachromosomal Translocation of PAX6 and Aniridia.
Reis LM +6 more
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Remote 1,5-Difunctionalization of Alkenes via a Sulfinyl-Smiles Rearrangement and Vinylcyclopropane Ring-Opening Cascade. [PDF]
Hu Y, Nitaj K, Nevado C.
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Linear RAG scanning mediates editing of Igκ variable region repertoires. [PDF]
Li X +13 more
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<i>RET</i> fusion partners dictate oncogenic potential in undifferentiated spindle cell sarcomas. [PDF]
Gui Q +12 more
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<i>CIC-DUX4</i> Rearranged Gastric Sarcoma Confirmed by Next-Generation Sequencing: A Case Report and Review of Literature. [PDF]
Hasegawa H +9 more
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Rapid chromosomal evolution and polycentromeric drive in sedges and rushes
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When a “Dimroth Rearrangement” Is Not a Dimroth Rearrangement
The Journal of Organic Chemistry, 2021In the Dimroth rearrangement of heterocycles, often pyrimidines, an exocyclic and a ring substituent are interchanged. However, the term Dimroth rearrangement is frequently used even when there is no knowledge of the reaction mechanism and alternatives are likely. Here, we have employed density functional theory (DFT) calculations at the M06-2X/6-311+G(
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An alternative procedure for isolation of 4β-phorbol from seeds of Croton tiglium has been developed, and an artifact containing a furan ring formed by rearrangement of 12,13,20- O-triacylated phorbol derivatives into (6b S,7 R,8 R,8a S)-2-(hydroxymethyl)-5,7,9,9-tetramethyl-3,7,8,9,9a,9b-hexahydrocyclopropa[3',4']benzo[1',2':3,4]cyclohepta[1,2- b ...
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