Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers
Thermal removal of neutral volatile linkers enables precise and solvent‐free generation of metal vacancies in MOFs. This strategy affords redox‐stable, coordinatively unsaturated FeII sites with tunable spin, ligand coordination, and catalytic behavior. The approach offers a general route to design defect‐functional materials through local coordination
Sonia Martínez‐Giménez +9 more
wiley +1 more source
Regional and educational disparities in inaccurately coded deaths in Sweden, 1997-2023: a systematic analysis. [PDF]
Gray A +7 more
europepmc +1 more source
Directional Flow of Confined Polaritons in CrSBr
CrSBr, a layered magnetic semiconductor, naturally channels self‐hybridized excitonpolaritons into highly directional flow. Its intrinsic optical anisotropy, high refractive index, and strong lightmatter coupling enable long‐range guided modes along the a‐axis, with propagation lengths set by their excitonphoton admixture.
Pratap Chandra Adak +10 more
wiley +1 more source
Comparing the Environmental Impacts of Representative Food Donation and Redistribution Strategies. [PDF]
Guo Z +6 more
europepmc +1 more source
In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts
An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea +9 more
wiley +1 more source
Iron-aluminum co-regulation of elemental partitioning and organic matrix remodeling shapes leaf chemical composition and quality traits in tea. [PDF]
Li H, Hu Z, Ai Z, Yang Y.
europepmc +1 more source
Sub‐Nanometer Curvature Unlocks Quantum Orbital Flexoelectricity in Graphene
In self‐assembled, reproducible, large‐area, quasi‐pristine graphene nanowrinkles, extreme curvature forces out‐of‐plane π‐electrons toward hybridization, driving a transition from classical to quantum orbital flexoelectricity. As curvature approaches the fundamental physical limit set by the C─C bond length, the resulting polarization increases by ...
Sathvik Ajay Iyengar +8 more
wiley +1 more source
Electric Field Effects on the Optoelectronic Properties of Fluorinated Heptyl-Bicyclohexyl-Biphenyl: A TD-DFT Investigation. [PDF]
Trabelsi J, Esboui M.
europepmc +1 more source

