Results 231 to 240 of about 292,957 (316)

Supramolecularly Directed Confined Crystallization of Lamellar Carbon Nitride for Efficient Photocatalytic Hydrogen Generation

open access: yesAdvanced Energy Materials, EarlyView.
ABSTRACT Sustainable hydrogen generation through water splitting is key to realizing a future hydrogen economy. In this study, we achieved molecular‐level control over self‐assembled supramolecular complexes of cyanuric acid and 3‐amino 1,2,4 triazole (AT) monomers. This was coupled with molten‐salt‐assisted thermal polymerization in a eutectic mixture
Nithinraj Panangattu Dharmarajan   +13 more
wiley   +1 more source

BNB/NBN‐Phenalenyl‐2'‐deoxyuridines as a Fluorophore–Quencher Pair in DNA

open access: yesAngewandte Chemie, EarlyView.
Two BN‐chromophore‐extended nucleosides containing electronically complementary BNB‐ and NBN‐doped phenalenyls were synthesised and incorporated into deoxyribonucleic acid (DNA) oligonucleotides. These chromophores act as an efficient fluorophore–quencher pair under aqueous conditions.
Sarah Lutz   +6 more
wiley   +2 more sources

3D Interconnected Zn‐Ion Pathways Through Anionic Nanochannels Surrounding Bacterial Cellulose Nanofibers by Repetitive Interfacial Assembly for Aqueous Zn‐Ion Battery Separators

open access: yesAdvanced Energy Materials, EarlyView.
A repetitive interfacial assembly method is introduced to prepare a nanofibrillar separator with interconnected 3D anionic nanochannels for aqueous zinc‐ion batteries. The carboxylate‐rich nanochannels promote enhancements of Zn2+ ion transport and charge transfer at the electrode surface, and the 3D nanostructured hydrogels contribute to homogeneous ...
Wonseok Choi   +6 more
wiley   +1 more source

Redox‐Mediated Stabilization of the Hole Transport Layer and Buried Interface Toward Stable Perovskite Solar Cells

open access: yesAngewandte Chemie, EarlyView.
A facile and effective strategy, that is, synergistic regulation of the NiOx/SAM buried interface via cesium oxalate (CsOA) modification, is developed. The CsOA treatment suppresses detrimental Ni4+ formation, promotes uniform SAM assembly, and aligns the energy levels at the hole‐transport layer/perovskite interface, enabling improved film ...
Jiarong Wang   +16 more
wiley   +2 more sources

Redox Complexity in Sodium Manganese Hexacyanomanganate and Its Influence on Sodium‐Ion Storage Performance

open access: yesAdvanced Energy Materials, EarlyView.
The role of each Mn site in the Na3‐xMn[Mn(CN)6]·zH2O compounds’ redox activity was investigated using a combined experimental–computational approach, which shows that only the low‐spin Mn‐C site undergoes redox changes (Mn1+ to Mn4+), while high‐spin Mn‐N remains unchanged. The study confirms the presence of the Mn1+ intermediate and newly reveals its
Zhenying Li   +11 more
wiley   +1 more source

Electrolyte Covalent Organic Frameworks for Exceptional Potassium Ion Conduction

open access: yesAngewandte Chemie, EarlyView.
One‐pot polymerization of monomers with oligo(ethylene oxide) side chains of different lengths creates electrolyte covalent organic frameworks with well‐defined K+‐electrolyte pathways in 1D pores for K+ conduction. The materials promote K+ conduction exponentially with the side chain length, achieve exceptional conductivity, and enable frictionless ...
Shanshan Tao   +4 more
wiley   +2 more sources

Solvent‐Induced Covalent Bond Softening Boosts Battery Voltage

open access: yesAngewandte Chemie, EarlyView.
The strong attractive interaction between the nucleophilic center of the solvent and the electrophilic region of the covalently bonded cathode fragment triggers charge transfer. This results in the electron population in the antibonding orbital of the covalent bond, leading to bond weakening and elongation, and consequently increasing the cathode ...
Yanyan Wang   +6 more
wiley   +2 more sources

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