Results 91 to 100 of about 5,081,569 (252)

Chemical Upcycling of Polyphenylene Sulfide at Room Temperature

open access: yesAdvanced Science, Volume 13, Issue 22, 17 April 2026.
Poly(phenylene sulfide) (PPS) is a semi‐crystalline super engineering plastic with exceptional properties. An iron‐photocatalyzed strategy is reported for chemical upcycling of PPS plastics at room temperature using 1,2‐dichloroethane. The method demonstrates remarkable efficiency across diverse PPS resins and post‐consumer composites, even within ...
Boning Gu, Chengliang Li, Xuefeng Jiang
wiley   +1 more source

Reductive dechlorination of tetrachloroethene by a stepwise catalysis of different organohalide respiring bacteria and reductive dehalogenases [PDF]

open access: yes, 2018
The enrichment culture SL2 dechlorinating tetrachloroethene (PCE) to ethene with strong trichloroethene (TCE) accumulation prior to cis-1,2-dichloroethene (cis-DCE) formation was analyzed for the presence of organohalide respiring bacteria and reductive ...
Charnay, Marie-Paule   +6 more
core  

Occurrence and Human Health Implications of Legacy Organochlorine Pesticides and Their Metabolites in Fruits and Vegetables of Bangladesh

open access: yesFood Safety and Health, Volume 4, Issue 2, Page 359-373, April 2026.
Multiple OCP isomers and/or metabolites along with their parent compounds were detected in commonly consumed fruits and vegetables of Bangladesh, possibly attributed to both recently and historically applied OCPs. However, all the detected values were below 0.01 mg/kg, indicating no potential human health risks through dietary intake. ABSTRACT Globally,
Kazi Sanjana Adnen   +4 more
wiley   +1 more source

Interference of TiO2 in Fricke Dosimetry: Adsorption Mechanisms and Dose Measurement Challenges under Gamma Irradiation

open access: yesChemistryOpen, Volume 15, Issue 4, April 2026.
The presence of TiO2 in Fricke dosimetric systems introduces complex interferences under gamma irradiation. Adsorption of Fe2+/Fe3+ ions, coupled with radiolytic and surface‐mediated processes, alters redox equilibria and apparent absorbed dose values, highlighting critical challenges in chemical dosimetry applied to heterogeneous radiolytic ...
William Villacis   +4 more
wiley   +1 more source

Development and Characterization of a Chloroethenes-Dechlorinating Consortium Using Gluconate as a Hydrogen Donor

open access: yesJournal of Water and Environment Technology, 2020
To evaluate the effectiveness of gluconate as a potential hydrogen donor for reductive dechlorination of chloroethenes, we developed a trichloroethene (TCE)-dechlorinating consortium from chloroethenes-contaminated groundwater containing Dehalococcoides ...
Yuta Fujii   +4 more
doaj   +1 more source

Opportunities for groundwater microbial electro-remediation [PDF]

open access: yes, 2018
Microbial Biotechnology published by John Wiley & Sons Ltd and Society for Applied Microbiology. Groundwater pollution is a serious worldwide concern. Aromatic compounds, chlorinated hydrocarbons, metals and nutrients among others can be widely found in ...
Balaguer i Condom, Maria Dolors   +3 more
core   +2 more sources

From Energy Deprivation Stress to Catalytic Adaptation of Reductive Dehalogenase TmrA for 1,1‐DCA Dechlorination: An Experimental and in Silico Study

open access: yesMicrobial Biotechnology, Volume 19, Issue 4, April 2026.
Adaptive evolution of Dehalobacter restrictus strain UNSWDHB under a ratio of 1:9 chloroform:1,1‐DCA regime increased 1,1‐DCA dechlorination. Sequencing and molecular dynamics simulation reveal high‐entropy tmrA mutations that improved 1,1‐DCA binding energy and stabilize the catalytic pocket, outlining a route to tune reductive dehalogenases for ...
Yi Ren   +3 more
wiley   +1 more source

Ultrafast reductive dechlorination of carbon tetrachloride by amorphous Fe78Si9B13 alloy

open access: yesResults in Physics, 2019
Amorphous Fe78Si9B13 ribbons and zero-valent iron (ZVI) powder were used to remove carbon tetrachloride (CTC) in the neutral oxic environment. The amorphous Fe78Si9B13 ribbons showed significantly better dechlorination performance than the ZVI powder ...
Changqin Zhang   +3 more
doaj   +1 more source

Reductive dechlorination of high concentrations of chloroethenes by a Dehalococcoides mccartyi strain 11G

open access: yesFEMS Microbiology Ecology, 2018
&NA; Chloroethenes are common groundwater and soil contaminants due to extensive historic utilization and inappropriate discharge. The tendency for chloroethenes to become sequestered as dense non‐aqueous phase liquids (DNAPL)—a point source to ...
Siyan Zhao, Jianzhong He
semanticscholar   +1 more source

Chlorinated Paracyclophanes: Composition Analysis and Direct Metal‐Free Alkylation with n‐BuLi

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 12, 23 March 2026.
A transition‐metal‐free alkylation of pseudo‐para dichloro[2.2]paracyclophane (Cl2‐PCP) is reported, utilizing the purified pseudo‐para isomer and n‐butyllithium (BuLi). Optimization with the chelating agent TMEDA and refluxing n‐heptane significantly boosted selectivity and reaction rate, providing the dialkylated product in 22% isolated yield.
Davide Frigatti   +3 more
wiley   +1 more source

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