Results 181 to 190 of about 193,388 (229)
Chemistry – A European Journal, EarlyView.Fluorinated poly(pyridyl)borates have been utilized to stabilize rhodium‐diene complexes and as supporting ligands in rhodium‐catalyzed redox‐neutral C–C silylation of cyclopropyl acetates, producing silicon‐containing heterocyclic products, dioxasilolanes.
Vo Quang Huy Phan +3 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.ABSTRACT Hexanuclear cyclic Gd(III) coordination compounds are promising candidates for magnetic and magnetocaloric applications, yet systematic series remain rare due to synthetic challenges. We report the synthesis and characterization of five new complexes with the general formula [Gd(H3bt)(carboxylate)]6, employing four different carboxylate ...
Ondřej František Fellner +7 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.This study reports six new copper(I) complexes with unusual coordination and strong anticancer activity against a panel of human cancer cell lines derived from different solid tumors. The most active compounds outperform cisplatin, even in resistant cells, by inhibiting protein disulfide isomerase and inducing redox stress that triggers non‐apoptotic ...
Vo Quang Huy Phan +9 more
wiley +1 more source
High‐Temperature Heat Pump Test Bench with n‐Butane (R‐600) Generating Steam
Chemie Ingenieur Technik, EarlyView.This work involves building a test bench for a high‐temperature heat pump (HTHP) and analyzing the measurements. The focus is on steam generation using an HTHP to decarbonize process steam demand. The findings indicate that stable steam generation is possible, providing a higher heat transfer coefficient in the heat pump's condenser.
Sebastian Benkert +7 more
wiley +1 more source
A Methodology to Integrate Closed‐Cycle Heat Pumps into Batch Distillation Columns
Chemie Ingenieur Technik, EarlyView.Batch distillation often cannot use vapor recompression due to contamination risks in food and pharma. This study proposes a design for integrating closed‐loop heat pumps using natural fluids. Results show significant energy savings, offering a sustainable alternative to traditional setups.
Philipp Dorn +5 more
wiley +1 more source
Chemie Ingenieur Technik, EarlyView.Thermal defrosting limits desublimator efficiency in freeze‐drying. This review and case study compares thermal versus mechanical regeneration, links frost properties and external heat transfer to energy demand, and summarizes pilot‐scale scraping results enabling single‐unit, continuous lyophilization.
Moritz Krummenacher +3 more
wiley +1 more source
The Canadian Journal of Chemical Engineering, EarlyView.Sodium alginate was modified with EDC/NHS for the immobilization of Yacon peel peroxidase, resulting in a novel biocatalyst for the oxidation of 2,4‐dichlorophenol. Abstract Yacon (Smallanthus sonchifolius) roots are emerging as an alternative source of peroxidase. This study aimed to extract, immobilize, and characterize the peroxidase from Yacon peel,
Mariana Gomes Oliveira +4 more
wiley +1 more source
The Canadian Journal of Chemical Engineering, EarlyView.Comparison of PSA and amine‐based absorption for syngas purification shows that PSA offers lower energy intensity, global warming potential, and minimum selling price, making it a more sustainable option. However, absorption achieves higher syngas purity. A GREENSCOPE‐based multi‐criteria assessment guides optimal process selection.
Magno Fonseca Santos +2 more
wiley +1 more source
The Canadian Journal of Chemical Engineering, EarlyView.Spouted bed drying of mango peels with colloidal SiO2 and corn starch produces a free‐flowing powder with reduced agglomeration, increased drying yield, and preserved antioxidant and polyphenol content. Abstract The production of polyphenol‐rich powders is a promising strategy for valorizing agro‐industrial byproducts. This study evaluated drying yield,
Guilherme Henrique Alves Pinto +3 more
wiley +1 more source