Results 111 to 120 of about 8,812 (304)

X‐Ray Photoelectron Spectroscopy as Useful Technique for the Quantification of Halogen and Chalcogen Bonding Interactions

open access: yesChemistryEurope, EarlyView.
Unprecedented application of X‐ray photoelectron spectroscopy (XPS) for quantifying halogen and chalcogen bond strengths. This pioneering work provides the first benchmark study and establishes strong correlations between XPS shifts (ΔBE) and interaction energies (ΔE), revealing XPS as an experimental measure for noncovalent bond quantification in ...
Sergi Burguera, Antonio Frontera
wiley   +1 more source

Aluminum versus Gallium: Differences in Bis(bis(trimethylsilyl)methyl) Element Halides, Hydrides, and Oxygen‐Bridged E/P Frustrated Lewis Pairs

open access: yesChemistryEurope, EarlyView.
Reacting Bis2GaBr (Bis = CH(SiMe3)2) with Bis2AlH selectively yields Bis2GaH, a monomeric hydride in solution, characterized by diffusion ordered spectroscopy NMR, infrared spectroscopy and indirectly via hydrogallation. A one‐pot route enables frustrated Lewis pairs Bis2EOPtBu2 (E = Al, Ga), with the gallium analog splitting H2 and showing a dynamic ...
Julian Buth   +7 more
wiley   +1 more source

Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth‐Ligand Cooperation

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Over the past twenty years, main group chemistry has significantly expanded its scope to include reactivities once considered the exclusive domain of transition metals. Among the emerging concepts, element‐ligand cooperation has proven to be a powerful strategy for enabling bond activation reactions but remains relatively unexplored for ...
Lennart Hensle, Viktoria H. Gessner
wiley   +1 more source

Spectroscopic Fingerprinting of Coordination‐driven Spin States in Metal‐organic Architectures

open access: yesChemistry – A European Journal, EarlyView.
Coordination geometry controls spin states in Co‐TCNQ frameworks. Combined theory and XAS confirm the high‐spin Co2+ on graphene and establish a direct approach for spin‐state assignment in metal‐organic systems. ABSTRACT Determining the local geometry of metal‐organic architecture on substrates is challenging, as substrate interactions can alter the ...
Yan Yan Grisan Qiu   +10 more
wiley   +1 more source

Distinct Ligand‐ and Metal‐Centered Phosphorescence in a Terbium Carbazolyl Complex

open access: yesChemistry – A European Journal, EarlyView.
Terbium and lanthanum carbazolide complexes show two distinct modes of luminescence: Strongly temperature‐dependent narrow‐line terbium emission could be induced. In addition, both the terbium and the lanthanum complexes show broad‐line interligand emission processes with excited states of microsecond life‐time.
Xiaofei Sun   +9 more
wiley   +1 more source

Attitude of Romanian Medical Students and Doctors toward Business Ethics: Analyzing the Influence of Sex, Age, and Ethics Education. [PDF]

open access: yesEur J Investig Health Psychol Educ, 2023
Constantin GD   +7 more
europepmc   +1 more source

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